Aluminium dodecaboride
Chemical compound
From Wikipedia, the free encyclopedia
Aluminium dodecaboride (AlB12) is a superhard chemical compound with 17% aluminium content by weight.
| Names | |
|---|---|
| IUPAC name
Aluminium dodecaboride | |
| Other names
AlB12 | |
| Identifiers | |
3D model (JSmol) |
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| ECHA InfoCard | 100.031.737 |
| EC Number |
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PubChem CID |
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| Properties | |
| AlB12 | |
| Molar mass | 156.714 g/mol[1] |
| Appearance | Yellow to black solid[1] |
| Density | 2.55 g/cm3[1] |
| Melting point | 2,070 °C (3,760 °F; 2,340 K)[1] |
| insoluble | |
| Solubility | soluble in hot nitric acid (decomposes),[2] soluble in nitric acid (decomposes),[3] soluble in sulfuric acid (decomposes)[3] |
| Structure | |
| Tetragonal (α-form) Orthorhombic (β-form) | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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It is the hardest boride of the aluminium-boron system, which also includes AlB10, AlB4, AlB2 and AlB.
Properties
Preparation
The β-form can be prepared by the reaction of boron(III) oxide with sulfur and aluminium, then adding carbon to the mixture.