Aurosilane

Chemical compound From Wikipedia, the free encyclopedia

Aurosilane is an inorganic compound with a chemical formula of SiAu4. In this compound, gold acts as an electron acceptor with a valence of –1. Aurosilane has been isolated as a type of gold silane.[1] Its unit cell parameters are a = 5.658, c = 5.605 A.[2] The LUMO and the four Si-Au bonding orbitals of SiAu4 are similar to those of SiH4.[3]

Quick facts Names, Identifiers ...
Aurosilane
Names
IUPAC name
Tetraaurosilane
Other names
Silicon tetraauride
Identifiers
3D model (JSmol)
  • InChI=1S/4Au.Si
    Key: HAWKSDAOUYSVMB-UHFFFAOYSA-N
  • [Au][Si]([Au])([Au])[Au]
Properties
SiAu4
Molar mass 675.159
Related compounds
Other anions
silane
Other cations
caesium auride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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In addition, silicon can also form other compounds with gold such as Si3Au3.[4]

References

External reading

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