Boroantimonate

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Boroantimonates are chemical compounds in which borate and antimonate groups share oxygen atoms. Known compounds are transparent. Antimony is in the +5 oxidation state and is in octahedral coordination by oxygen.[1]

List

More information name, formula ...
name formula mw crystal system space group unit cell Å volume density comment references
SbB3O6 414.11 monoclinic C2 a=7.143 b=4.953 c=6.393 β=105.70 Z=2 217.71 3.816 band gap 4.083 eV; birefringence Δn=0.290 at 546 nm; NLO 3.5 × KH2PO4 [2]
Na2SbB3O8 328.16 monoclinic P21/c a=5.8278 b=10.3521 c=10.4775 β=102.948° Z=4 616.04 3.538 colourless [3]
KSbB2O6 monoclinic Cc a=11.458 b=7.019 c=7.324 β=124.413° [4]
K2SbB3O8 360.38 monoclinic P21/c a=5.9013 b=11.088 c=10.950 β=103.218° Z=4 697.5 3.432 colourless [3][5]
α-K3Sb4BO13 823.11 monoclinic C2/m a=12.2032 b=7.4881 c=13.070 β=101.636° Z=4 1169.8 4.674 200K [6]
β-K3Sb4BO13 823.11 triclinic P1 a=7.1168 b=7.211 c=13.2218 α=81.923 β=99.760 γ=117.10 Z=2 593.79 4.602 250K [6]
β-RbSbB2O6 324.84 monoclinic Cc a=11.715 b=7.1633 c=7.4109 β=125.43° 506.71 4.258 colourless [3]
Rb2SbB3O8 453.12 monoclinic P21/c a=5.9381 b=11.2928 c=11.318 β=103.7° Z=4 737.2 4.083 colourless [3]
KRb2Sb4BO13 916.31 triclinic P1 a=7.1456 b=7.2390 c=13.4113 α=82.058 β=100.051 γ=117.205 Z=2 606.16 5.020 colourless [7]
Rb3Sb4BO13 962.22 triclinic P1 a=7.1593 b=7.2533 c=13.4894 α=82.358° β=99.999° γ=117.321° Z=2 611.75 5.224 colourless [7]
BaSb2B4O12 monoclinic C2/c a=6.9818 b=11.8452 c=11.089 β=102.772° [4]
SmBSb2O8 orthorhombic Pnma a=12.6155 b=7.2702 c=12.7086 [8]
EuBSb2O8 orthorhombic Pnma a=12.5730 b=7.2605 c=12.6920 [8]
GdBSb2O8 orthorhombic Pnma a=12.5594 b=7.2369 c=12.6913 [8]
TbBSb2O8 orthorhombic Pnma a=12.532 b=7.236 c=12.671 [8]
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