Dimethylphosphite
Chemical compound
From Wikipedia, the free encyclopedia
Dimethylphosphite is an organophosphorus compound with the formula (CH3O)2P(O)H, known as dimethyl hydrogen phosphite (DMHP). Dimethylphosphite, is a minor tautomer of the phosphorus(V) derivative. It is a reagent for generating other organophosphorus compounds, exploiting the high reactivity of the P-H bond. The molecule is tetrahedral. It is a colorless liquid. The compounds can be prepared by methanolysis of phosphorus trichloride or by heating diethylphosphite in methanol.[1]
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| Names | |
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| Preferred IUPAC name
Dimethyl phosphonate | |
| Other names
Phosphonic acid, dimethyl ester | |
| Identifiers | |
3D model (JSmol) |
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| ChEMBL | |
| ChemSpider | |
| ECHA InfoCard | 100.011.622 |
PubChem CID |
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| UNII | |
CompTox Dashboard (EPA) |
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| Properties | |
| C2H7O3P | |
| Molar mass | 110.049 g·mol−1 |
| Appearance | colorless liquid |
| Density | 1.20 g/cm3 |
| Boiling point | 170–171 °C (338–340 °F; 443–444 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Although studies have not been reported for this compound, the closely related diethylphosphite exists predominantly as the phosphorus(V) tautomer.[2]