Isotopes of francium

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Francium (87Fr) has no stable isotopes, so a standard atomic weight cannot be given. Its most stable isotope is 223Fr with a half-life of 22 minutes, occurring in trace quantities in nature as an intermediate decay product of 235U.

Quick facts Main isotopes, Decay ...
Isotopes of francium (87Fr)
Main isotopes[1] Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
212Fr synth 20.0 min β+ 212Rn
α 208At
221Fr trace 4.801 min α 217At
β 221Ra
222Fr synth 14.2 min β 222Ra
223Fr trace 22.00 min β 223Ra
α 219At
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Of elements whose most stable isotopes have been identified with certainty, francium is the most unstable, though astatine is the rarest in nature due to its naturally occurring isotopes having even shorter half-lives and even smaller branching ratios.

The elements with atomic number of 106 (seaborgium) or greater have their longest known half-life of any isotope shorter than that of francium, but as those elements have only isotopes on the proton-rich side of beta stability discovered, there is a strong possibility that undiscovered isotopes of these elements will have longer half-lives that could exceed that of francium-223.

List of isotopes


More information Nuclide, Historic name ...
Nuclide
[n 1]
Historic
name
Z N Isotopic mass (Da)[2]
[n 2][n 3]
Discovery
year[3][4]
Half-life[1]
[n 4]
Decay
mode
[1]
[n 5]
Daughter
isotope

Spin and
parity[1]
[n 6][n 4]
Isotopic
abundance
Excitation energy[n 4]
197Fr 87 110 197.01101(6) 2013 2.3(19) ms α 193At (7/2−)
198Fr 87 111 198.01028(3) 2013 15(3) ms α 194At 3+#
198mFr[n 7] 0(50) keV 2013 1.1(7) ms α 194At (10−)
199Fr 87 112 199.007269(15) 1999 6.6(22) ms α 195At 1/2+#
199m1Fr 45(13) keV 2013 6.5(9) ms α 195At 7/2−#
199m2Fr 250(50)# keV 2013 2.2(12) ms α 195At 13/2+#
200Fr 87 113 200.00658(3) 1995 47.5(28) ms α 196At (3+)
200m1Fr[n 7] 50(60) keV 2014 190(120) ms α 196At 10−#
200m2Fr 150(50)# keV (2014)[n 8] 790(360) ns
201Fr 87 114 201.003852(10) 1980 62.8(19) ms α 197At 9/2−
201m1Fr 129(10) keV 2005 24(6) ms α 197At 1/2+
201m2Fr 289.5(4) keV 2014 720(40) ns IT 201Fr 13/2+
202Fr 87 115 202.003330(6) 1980 372(12) ms α 198At 3+
202mFr 257(6) keV 1992 286(13) ms α 198At 10−
IT (?%) 202Fr
203Fr 87 116 203.000941(7) 1967 550(10) ms α 199At 9/2−
203m1Fr 361(6) keV 2013 43(4) ms IT (80%) 203Fr 1/2+
α (20%) 199At
203m2Fr 426.0(10) keV 2013 370(50) ns IT 203Fr 13/2+
204Fr 87 117 204.000652(26) 1964 1.75(26) s α (96%) 200At 3+
β+ (4%) 204Rn
204m1Fr 50(4) keV 1967 2.41(19) s α (90%) 200At 7+
β+ (10%) 204Rn
204m2Fr 326(4) keV 1992 1.65(15) s α (53%) 200At 10−
IT (47%) 204Fr
205Fr 87 118 204.998594(8) 1964 3.90(7) s α (98.5%) 201At 9/2−
β+ (1.5%) 205Rn
205m1Fr 544.0(10) keV 2012 80(20) ns IT 205Fr 13/2+
205m2Fr 609(6) keV 2012 1.15(4) ms IT 203Fr (1/2+)
206Fr 87 119 205.998661(30) 1964 ~16 s α (88.4%) 202At 3+
β+ (11.6%) 206Rn
206m1Fr 200(40) keV 1981 ~16 s α (84.7%) 202At 7+
β+ (?%) 206Rn
IT (?%) 206Fr
206m2Fr 730(40) keV 1981 700(100) ms IT (87%) 206Fr 10−
α (13%) 202At
207Fr 87 120 206.996941(19) 1964 14.8(1) s α (95%) 203At 9/2−
β+ (5%) 207Rn
208Fr 87 121 207.997139(13) 1964 59.1(3) s α (89%) 204At 7+
β+ (11%) 208Rn
208mFr 826.3(5) keV 2009 432(11) ns IT 208Fr 10−
209Fr 87 122 208.995940(12) 1964 50.5(7) s α (89%) 205At 9/2−
β+ (11%) 209Rn
209mFr 4659.8(7) keV 2006 420(18) ns IT 209Fr 45/2−
210Fr 87 123 209.996411(14) 1964 3.18(6) min α (71%) 206At 6+
β+ (29%) 210Rn
210mFr 4417.2(10) keV 2016 475(6) ns IT 210Fr (23)+
211Fr 87 124 210.995555(13) 1964 3.10(2) min α (87%) 207At 9/2−
β+ (13%) 211Rn
211m1Fr 2423.16(24) keV 1986 146(14) ns IT 211Fr 29/2+
211m2Fr 4657.3(4) keV 1986 124.5(12) ns IT 211Fr 45/2−
212Fr 87 125 211.996225(9) 1950 20.0(6) min β+ (57%) 212Rn 5+
α (43%) 208At
212m1Fr 1551.4(3) keV 1990 31.9(7) μs IT 212Fr 11+
212m2Fr 2492.2(4) keV 1977 604(28) ns IT 212Fr 15−
212m3Fr 5854.7(6) keV 1986 312(21) ns IT 212Fr 27−
212m4Fr 8533.4(11) keV 1990 23.6(21) μs IT 212Fr 34+#
213Fr 87 126 212.996184(5) 1964 34.14(6) s α (99.44%) 209At 9/2−
β+ (0.56%) 213Rn
213m1Fr 1590.41(18) keV 1976 505(14) ns IT 213Fr 21/2−
213m2Fr 2537.62(23) keV 1976 238(6) ns IT 213Fr 29/2+
213m3Fr 8094.8(7) keV 1989 3.1(2) μs IT 213Fr (65/2−)
214Fr 87 127 213.998971(9) 1966 5.51(13) ms α 210At (1−)
214m1Fr 121(5) keV 1968 3.35(5) ms α 210At (8−)
214m2Fr 638(5) keV 1994 103(4) ns IT 214Fr (11+)
214m3Fr 6577(100)# keV 1994 108(7) ns IT 214Fr (33+)
215Fr 87 128 215.000342(8) 1970 90(4) ns α 211At 9/2−
216Fr 87 129 216.003190(4) 1970 700(20) ns α 212At (1−)
216mFr 219(6) keV 2007 850(30) ns α 212m1At[5] (9−)
217Fr 87 130 217.004632(7) 1968 22(5) μs α 213At 9/2−
218Fr 87 131 218.007579(5) 1949 1.4(5) ms α 214At 1−
218mFr 87(4) keV 1982 21.9(5) ms α 214At (8−)
219Fr 87 132 219.009251(7) 1948 22.5(17) ms α 215At 9/2−
220Fr 87 133 220.012327(4) 1948 27.4(3) s α (99.65%) 216At 1+
β (0.35%) 220Ra
221Fr 87 134 221.014254(5) 1947 4.801(5) min α 217At 5/2− Trace[n 9]
β (0.0048%) 221Ra
CD (8.8×10−11%)[n 10] 207Tl
14C
222Fr 87 135 222.017583(8) 1975 14.2(3) min β[n 11] 222Ra 2−
223Fr Actinium K 87 136 223.0197342(21) 1939 22.00(7) min β 223Ra 3/2− Trace[n 12]
α (0.006%) 219At
224Fr 87 137 224.023348(12) 1969 3.33(10) min β 224Ra 1−
225Fr 87 138 225.025572(13) 1969 3.95(14) min β 225Ra 3/2−
226Fr 87 139 226.029545(7) 1969 48.5(7) s β 226Ra 1−
227Fr 87 140 227.031865(6) 1972 2.47(3) min β 227Ra 1/2+
228Fr 87 141 228.035839(7) 1972 38(1) s β 228Ra 2−
228mFr 1004(30) keV (2008)[n 13] 180(110) s
229Fr 87 142 229.038291(5) 1975 50.2(4) s β 229Ra (1/2+)
230Fr 87 143 230.042391(7) 1987 19.1(5) s β 230Ra 2+#
231Fr 87 144 231.045175(8) 1985 17.6(6) s β 231Ra (1/2+)
232Fr 87 145 232.049461(15) 1990 5.5(6) s β 232Ra (5)
233Fr 87 146 233.052518(21) 2010 900(100) ms β 233Ra 1/2+#
This table header & footer:
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  1. mFr  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. () spin value  Indicates spin with weak assignment arguments.
  6. Order of ground state and isomer is uncertain.
  7. Isomer had only been suggested, not included in discovery database
  8. Intermediate decay product of 237Np
  9. The nuclide with the lowest atomic number known to undergo cluster decay
  10. Theoretically capable of α decay to 218At with a partial half-life of ~1 d (branching ratio ~1%).[6]
  11. Intermediate decay product of 235U
  12. Only published in a conference proceeding and not a refereed journal

References

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