Kozeny–Carman equation

The equation is given as:^[4][5]

${\displaystyle {\frac {\Delta P}{L}}={\frac {150\mu }{{\mathit {\Phi }}_{\mathrm {s} }^{2}d_{\mathrm {p} }^{2}}}{\frac {(1-\varepsilon )^{2}}{\varepsilon ^{3}}}V_{\mathrm {0} }}$

where:

• ${\displaystyle \Delta P}$ is the pressure drop;
• ${\displaystyle L}$ is the total height of the bed;
• ${\displaystyle \mu }$ is the viscosity of the fluid;
• ${\displaystyle \varepsilon }$ is the porosity of the bed (${\displaystyle \simeq 0.37}$ for randomly packed spheres); ^[6]
• ${\displaystyle {\mathit {\Phi }}_{\mathrm {s} }}$ is the sphericity of the particles in the packed bed (${\displaystyle {\mathit {\Phi }}_{\mathrm {s} }}$ = 1.0 for spherical particles);
• ${\displaystyle d_{\mathrm {p} }}$ is the diameter of the volume equivalent spherical particle;
• ${\displaystyle V_{\mathrm {0} }}$ is the superficial or "empty-tower" velocity which is directly proportional to the average volumetric fluid flux in the channels (q), and porosity (${\displaystyle \mathbf {\varepsilon } }$). ^[7]

This equation holds for flow through packed beds with particle Reynolds numbers up to approximately 1.0, after which point frequent shifting of flow channels in the bed causes considerable kinetic energy losses.

This equation is a particular case of Darcy's law, with a very specific permeability. Darcy's law states that "flow is proportional to the pressure gradient and inversely proportional to the fluid viscosity" and is given as:

q ${\displaystyle ={\frac {\kappa }{\mu }}{\frac {\Delta P}{L}}}$

Combining these equations gives the final Kozeny equation for absolute (single phase) permeability:

${\displaystyle \kappa ={\mathit {\Phi }}_{\mathrm {s} }^{2}{\frac {\varepsilon ^{3}d_{\mathrm {p} }^{2}}{150(1-\varepsilon )^{2}}}}$

where:

• ${\displaystyle \kappa }$ is the absolute (i.e., single phase) permeability.

The equation was first^[8] proposed by Kozeny (1927)^[1] and later modified by Carman (1937, 1956).^[2][3] A similar equation was derived independently by Fair and Hatch in 1933.^[9] A comprehensive review of other equations has been published.^[10]

• Fractionating column
• Random close pack
• Raschig ring
• Ergun equation