Promethium(III) iodide

Chemical compound From Wikipedia, the free encyclopedia

Promethium(III) iodide is an inorganic compound, with the chemical formula of PmI3. It is a red radioactive solid with a melting point of 695 °C.[1]

Quick facts Names, Identifiers ...
Promethium(III) iodide
Names
Other names
Promethium iodide
Promethium triiodide
Identifiers
3D model (JSmol)
  • InChI=1S/3HI.Pm/h3*1H;/q;;;+3/p-3
    Key: CCGSLKOPQLRTPK-UHFFFAOYSA-K
  • [I-].[I-].[I-].[Pm+3]
Properties
PmI3
Appearance red solid[1]
Melting point 695 °C[1]
Related compounds
Other anions
promethium(III) fluoride
promethium(III) chloride
promethium(III) bromide
Other cations
neodymium(III) iodide
samarium(III) iodide
Related compounds
promethium diiodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation

Promethium(III) iodide is obtained by reacting anhydrous hydrogen iodide and promethium(III) chloride at a high temperature:

PmCl3 + 3 HI → PmI3 + 3 HCl[2]

From the reaction of a HI-H2 mixture and promethium oxide (Pm2O3), promethium(III) iodide cannot be produced, and only promethium oxyiodide (PmOI) can be obtained. Promethium oxide reacts with molten aluminum iodide at 500 °C to form promethium iodide.[3][4]

References

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