Trehalulose

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Trehalulose
Names
IUPAC name
1-O-α-D-Glucopyranosyl-D-fructose
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.051.967 Edit this at Wikidata
EC Number
  • 257-183-7
KEGG
UNII
  • InChI=1S/C12H22O11/c13-1-4(15)7(17)8(18)5(16)3-22-12-11(21)10(20)9(19)6(2-14)23-12/h4,6-15,17-21H,1-3H2/t4-,6-,7-,8-,9-,10+,11-,12+/m1/s1 checkY
    Key: NMELTECMHKKXLF-DGQJZECASA-N
  • C(C1C(C(C(C(O1)OCC(=O)C(C(C(CO)O)O)O)O)O)O)O
Properties
C12H22O11
Molar mass 342.297 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Trehalulose is a disaccharide made up of a molecule of fructose bound to a molecule of glucose. Like isomaltulose, it is a structural isomer of sucrose that is present in small quantities in honey.[1] It makes up 50% of sugars in the honeydew of silverleaf whiteflies[2][3] and is synthesised from sucrose by some bacteria,[4][5] such as Protaminombacter rubrum.[6][1] Because the anomeric carbon of the fructose moiety is not involved in the glycosidic bond, it is a reducing sugar.[6]

Because the fructose and glucose molecules are linked by a 1,1 glycosidic bond, which is more stable than the 1,2 glycosidic bond in sucrose, it is broken down more slowly than sucrose in the small intestine, giving it a lower glycemic index.[6] This more stable bond also means that it cannot be utilised by Streptococcus mutans, and it is therefore non-cariogenic.[7]

Properties

Honey from stingless bees

References

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