1,1'-Ferrocenetrisulfide

Chemical compound From Wikipedia, the free encyclopedia

1,1'-Ferrocenetrisulfide is the organoiron compound with the formula Fe(C5H4S)2S. A yellow solid, it is the simplest polysulfide derivative of ferrocene. It can be synthesized by treatment of dilithioferrocene with elemental sulfur.[2] Using proton NMR spectroscopy, the relatively slow conformational flexing of the trisulfide ring can be established.

Conformational equilibrium for ferrocene-1,1'-trisulfide.
Quick facts Names, Identifiers ...
1,1'-Ferrocenetrisulfide
Names
IUPAC name
1,2,3-Trithio[3]ferrocenophane
Other names
1,1'-trithiaferrocenophane
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C10H8S3.Fe/c1-2-6-9(5-1)11-13-12-10-7-3-4-8-10;/h1-8H;/q-2;+2
    Key: CGYCAYDFUFZJRS-UHFFFAOYSA-N
  • [CH-]1C=CC=C1SSS[C-]2C=CC=C2.[Fe+2]
Properties
C10H8FeS3
Molar mass 280.20 g·mol−1
Appearance Yellow solid
Density 1.887 g/cm3[1]
Melting point 149.5–150.5 Â°C (301.1–302.9 Â°F; 422.6–423.6 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 Â°C [77 Â°F], 100 kPa).
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