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Cerium monosulfide

Chemical compound From Wikipedia, the free encyclopedia

Cerium monosulfide is a binary inorganic compound of cerium and sulfur with the chemical formula CeS.[1][2][3][4] This is the simplest of cerium sulfides.

Quick facts Names, Identifiers ...
Cerium monosulfide
Names
Other names
Cerium sulfide (CeS)
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Ce.S
    Key: INJMJSIZAXAEMH-UHFFFAOYSA-N
  • S=[Ce]
Properties
CeS
Molar mass 172.18 g·mol−1
Appearance Yellow crystalline solid
Density 5.9 g/cm3
Melting point 2,445 °C (4,433 °F; 2,718 K)
insoluble
Structure
cubic
Related compounds
Other anions
Cerium monoselenide
Cerium monotelluride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Ce2S3 + CeH2 → 3CeS + H2
Ce + S → CeS

Physical properties

Cerium sulfide forms golden cubic crystals, with space group Fm3m and lattice parameter a = 5.763 Å. It has a NaCl-type structure.[7]

The compound melts congruently at a temperature of 2450 °C, the highest out of any known sulfide.[6]

Chemical properties

Cerium monosulfide has a wetting effect on metals, and it is relatively stable to metals other than platinum. It can react violently with platinum to form an intermetallic compound, platinum cerium.[5]

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