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Chromium azide

Chemical compound From Wikipedia, the free encyclopedia

Chromium azide is an inorganic chemical compound with the formula Cr(N3)3.

Quick facts Names, Identifiers ...
Chromium azide
Names
IUPAC name
Chromium(III) triazide
Other names
  • Chromium(III) azide
  • Chromium triazide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Cr.3N3/c;3*1-3-2/q+3;3*-1
    Key: QTGXYCYBAVYYCM-UHFFFAOYSA-N
  • [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[Cr+3]
Properties
Cr(N3)3
Molar mass 178.06 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Properties

Chromium azide formation has been investigated from chromium salts and sodium azide. It was separated in 1922 through the evaporation of a dry crystalline chromium(III) nitrate solution in absolute alcohol with sodium azide.[1] Through a spectrophotometric study, it was shown that the chromium(III) nitrate solution's green color was due to the mono-azido-chromium(III) complex. Two absorbency maxima were located at 442 and 605 nm.[1] Chromium azide has luminescence properties from its optically active Cr3+ ions.[2]

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