Chromium(III) hydroxide

Chemical compound (Cr(OH)3) From Wikipedia, the free encyclopedia

Chromium(III) hydroxide is a gelatinous green inorganic compound with the chemical formula Cr(OH)3. It is a polymer with an undefined structure and low solubility. It is amphoteric, dissolving in both strong alkalis and strong acids.[2]

Quick facts Names, Identifiers ...
Chromium(III) hydroxide
Names
IUPAC name
Chromium(3+) hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.781 Edit this at Wikidata
RTECS number
  • GB2670000
UNII
  • InChI=1S/Cr.3H2O/h;3*1H2
    Key: LXMQZGGLHVSEBA-UHFFFAOYSA-N
  • ionic form: [OH-].[OH-].[OH-].[Cr+++]
  • coordination form: O[Cr](O)O
Properties
Cr(OH)3
Molar mass 103.017 g·mol−1
Appearance green, gelatinous precipitate
Density 3.11 g/cm3
insoluble
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3[1]
REL (Recommended)
TWA 0.5 mg/m3[1]
IDLH (Immediate danger)
250 mg/m3[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation

Chromium(III) hydroxide is prepared by treating an aqueous solution of hydrated chromium trichloride with ammonia.[3]

It can also be prepared by treating an aqueous solution of chromium(III) nitrate with potassium hydroxide until the pH is within 7 to 8:[4] The following idealized equation suffices:

Cr(NO3)3 + 3 KOH → Cr(OH)3 + 3 KNO3

Use

It is used as a pigment, as a mordant, and as a catalyst for organic reactions.[5]

Natural occurrence

Three chromium(III) oxide hydroxide (CrO(OH)) minerals are known: bracewellite, grimaldiite and guyanaite.[6][7][8][9]

References

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