Curium(III) iodide

Chemical compound From Wikipedia, the free encyclopedia

Curium(III) iodide is a salt with the formula CmI3.[1][2][3] Since all isotopes of curium are only artificially produced, the compound has no natural occurrence.

Quick facts Names, Identifiers ...
Curium(III) iodide
Names
Other names
Curium triiodide
Identifiers
3D model (JSmol)
  • InChI=1S/Cm.3HI/h;3*1H/q+3;;;/p-3
    Key: UVXBBRRWLDYFRE-UHFFFAOYSA-K
  • [I-].[I-].[I-].[Cm+3]
Properties
CmI3
Molar mass 628 g·mol−1
Appearance white crystals
Related compounds
Related compounds
Americium triiodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Elemental curium and iodine can be reacted to synthesize curium(III) iodide.[4]

2Cm + 3I2 → 2CmI3

Also by the reaction of curium(III) chloride with ammonium iodide:[5][6]

CmCl3 + 3NH4I → CmI3 + 3NH4Cl

Physical properties

Curium(III) iodide is a colorless ionic compound consisting of Cm3+ and I ions. It forms white crystals the hexagonal crystal system in the space group R3 (space group no. 148) with the lattice parameters a = 744 pm and c = 2040 pm with six units per unit cell. Its crystal structure is isotypic with that of bismuth(III) iodide.[5][7]

References

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