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Einsteinium trifluoride

Chemical compound From Wikipedia, the free encyclopedia

Einsteinium fluoride is a binary inorganic chemical compound of einsteinium and fluorine with the chemical formula EsF3.[1]

Quick facts Names, Identifiers ...
Einsteinium fluoride
Names
Other names
Einsteinium(III) fluoride, einsteinium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Es.3FH/h;3*1H/q+3;;;/p-3
    Key: NYNVZWGCTJTDET-UHFFFAOYSA-K
  • [Es+3].[F-].[F-].[F-]
Properties
EsF3
Molar mass 309 g·mol−1
Appearance crystals
insoluble
Related compounds
Related compounds
Californium(III) fluoride
Berkelium(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Einsteinium fluoride can be precipitated from einsteinium(III) chloride solutions upon reaction with fluoride ions. An alternative preparation procedure is to expose einsteinium(III) oxide to chlorine trifluoride (ClF3) or F2 gas at a pressure of 1–2 atmospheres and a temperature between 300 and 400 °C. The EsF3 crystal structure is hexagonal, as in californium(III) fluoride (CfF3) where the Es3+ ions are 8-fold coordinated by fluorine ions in a bicapped trigonal prism arrangement.[2][3][4]

Physical properties

The compound forms crystals and is insoluble in water.[5]

Chemical properties

The compound is reduced by metallic lithium:[6][7]

EsF3 + 3Li → Es + 3 LiF

References

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