Isotopes of europium

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Naturally occurring europium (63Eu) is composed of two isotopes, 151Eu and 153Eu, with 153Eu being the more abundant (52.2% natural abundance). While 153Eu is observationally stable, 151Eu was found in 2007 to be unstable and undergo alpha decay;[4][5] its measured half-life of 4.6 × 1018 years corresponds to 1 alpha decay per two minutes per kilogram of natural europium, so for practical purposes it can be considered stable. Besides the natural radioisotope 151Eu, artificial radioisotopes from 130Eu to 170Eu have been made, with the most stable being 150Eu with a half-life of 36.9 years, 152Eu with a half-life of 13.517 years, 154Eu with a half-life of 8.592 years, and 155Eu with a half-life of 4.742 years. All the others have half-lives shorter than 100 days, with the majority shorter than 3 minutes.

Quick facts Main isotopes, Decay ...
Isotopes of europium (63Eu)
Main isotopes[1] Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
150Eu synth 36.9 y β+ 150Sm
151Eu 47.8% 4.6×1018 y α 147Pm
152Eu synth 13.517 y β+ 152Sm
β 152Gd
153Eu 52.2% stable
154Eu synth 8.592 y β 154Gd
ε 154Sm
155Eu synth 4.742 y β 155Gd
Standard atomic weight Ar°(Eu)
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This element also has 27 metastable isomers, with the most stable being 150mEu (12.8 hours), 152m1Eu (9.3116 hours) and 152m5Eu (96 minutes). The primary decay mode for isotopes lighter than 153Eu is electron capture to samarium isotopes, and the primary mode for heavier isotopes is beta minus decay to gadolinium isotopes. 152Eu and 154Eu can decay either way, as can 150mEu (meta state only).

List of isotopes


More information Nuclide, Z ...
Nuclide
[n 1]
Z N Isotopic mass (Da)[6]
[n 2][n 3]
Discovery
year[7][8]
Half-life[1]
[n 4][n 5]
Decay
mode
[1]
[n 6]
Daughter
isotope

[n 7][n 8]
Spin and
parity[1]
[n 9][n 5]
Natural abundance (mole fraction)
Excitation energy[n 5] Normal proportion[1] Range of variation
130Eu 63 67 129.96402(58)# 2004 1.0(4) ms p 129Sm (1+)
131Eu 63 68 130.95763(43)# 1998 17.8(19) ms p (89%) 130Sm 3/2+
β+ (?%) 131Sm
β+, p (?%) 130Pm
132Eu[9] 63 69 131.95470(43)# 2026 100# ms
[>310 ns]
1+#
133Eu[9] 63 70 132.94929(32)# 2026 200# ms
[>310 ns]
5/2+#
134Eu 63 71 133.94654(32)# 1989 0.5(2) s β+ 134Sm
β+, p (?%) 133Pm
135Eu 63 72 134.94187(21)# 1989 1.5(2) s β+ 135Sm 5/2+#
136Eu 63 73 135.93962(21)# 1987 3.3(3) s β+ (99.91%) 136Sm 6+#
β+, p (0.09%) 135Pm
136mEu[n 10] 100(100)# keV 1989 3.8(3) s β+ (99.91%) 136Sm 1+#
β+, p (0.09%) 135Pm
137Eu 63 74 136.9354307(47) 1982 8.4(5) s β+ 137Sm 5/2+#
138Eu 63 75 137.933709(30) 1982 5# s 2−#
138mEu[n 10] 100(50)# keV 1999 12.1(6) s β+ 138Sm 7−#
139Eu 63 76 138.929792(14) 1975 17.9(6) s β+ 139Sm (11/2)−
139mEu 148.3(3) keV 2011 10(2) μs IT 139Eu (7/2+)
140Eu 63 77 139.928088(55) 1982 1.51(2) s β+ (95.1%) 140Sm 1+
EC (4.9%)
140m1Eu 210(14) keV 1991 125(2) ms IT (>99%) 140Eu (5−)
β+ (>1%) 140Sm
140m2Eu 669(14) keV 2002 299.8(21) ns IT 140Eu (8+)
141Eu 63 78 140.924932(14) 1977 40.7(7) s β+ 141Sm 5/2+
141mEu 96.45(7) keV 1977 2.7(3) s IT (86%) 141Eu 11/2−
β+ (14%) 141Sm
142Eu 63 79 141.923447(32) 1966 2.36(10) s β+ (89.9%) 142Sm 1+
EC (11.1%) 142Sm
142mEu 450(30) keV 1975 1.223(8) min β+ 142Sm 8−
143Eu 63 80 142.920299(12) 1965 2.59(2) min β+ 143Sm 5/2+
143mEu 389.51(4) keV 1976 50.0(5) μs IT 143Eu 11/2−
144Eu 63 81 143.918819(12) 1965 10.2(1) s β+ 144Sm 1+
144mEu 1127.6(6) keV 1976 1.0(1) μs IT 144Eu 8−
145Eu 63 82 144.9162727(33) 1951 5.93(4) d β+ 145Sm 5/2+
145mEu 716.0(3) keV 1975 490(30) ns IT 145Eu 11/2−
146Eu 63 83 145.9172109(65) 1957 4.61(3) d β+ 146Sm 4−
146mEu 666.33(11) keV 1962 235(3) μs IT 146Eu 9+
147Eu 63 84 146.9167524(28) 1951 24.1(6) d β+ 147Sm 5/2+
α (0.0022%) 143Pm
147mEu 625.27(5) keV 1960 765(15) ns IT 147Eu 11/2−
148Eu 63 85 147.918091(11) 1951 54.5(5) d β+ 148Sm 5−
α (9.4×10−7%) 144Pm
148mEu 720.4(3) keV 1980 162(8) ns IT 148Eu 9+
149Eu 63 86 148.9179369(42) 1959 93.1(4) d EC 149Sm 5/2+
149mEu 496.386(2) keV 1960 2.45(5) μs IT 149Eu 11/2−
150Eu 63 87 149.9197071(67) 1950 36.9(9) y β+ 150Sm 5−
150mEu 41.7(10) keV 1961 12.8(1) h β (89%) 150Gd 0−
β+ (11%) 150Sm
IT (<5×10−8%)[10] 150Eu
151Eu[n 11][n 12] 63 88 150.9198566(13) 1933 4.6(12)×1018 y α 147Pm 5/2+ 0.4781(6)
151mEu 196.245(10) keV 1958 58.9(5) μs IT 151Eu 11/2−
152Eu 63 89 151.9217510(13) 1938 13.517(6) y β+ (72.08%) 152Sm 3−
β (27.92%) 152Gd
152m1Eu 45.5998(4) keV 1947 9.3116(13) h β (73%) 152Gd 0−
β+ (27%) 152Sm
152m2Eu 65.2969(4) keV 1978 940(80) ns IT 152Eu 1−
152m3Eu 78.2331(4) keV 1978 165(10) ns IT 152Eu 1+
152m4Eu 89.8496(4) keV 1965 384(10) ns IT 152Eu 4+
152m5Eu 147.86(10) keV 1963 95.8(4) min IT 152Eu 8−
153Eu[n 11] 63 90 152.9212368(13) 1933 Observationally Stable[n 13][11][12] 5/2+ 0.5219(6)
153mEu 1771.0(4) keV 2000 475(10) ns IT 153Eu 19/2−
154Eu[n 11] 63 91 153.9229857(13) 1947 8.592(3) y β (99.98%) 154Gd 3−
EC (0.02%) 154Sm
154m1Eu 68.1702(4) keV 1965 2.2(1) μs IT 154Eu 2+
154m2Eu 145.3(3) keV 1975 46.3(4) min IT 154Eu (8−)
155Eu[n 11] 63 92 154.9228998(13) 1951 4.742(8) y β 155Gd 5/2+
156Eu[n 11] 63 93 155.9247630(38) 1951 15.19(8) d β 156Gd 0+
157Eu 63 94 156.9254326(45) 1951 15.18(3) h β 157Gd 5/2+
158Eu 63 95 157.9277822(22) 1951 45.9(2) min β 158Gd 1−
159Eu 63 96 158.9290995(46) 1961 18.1(1) min β 159Gd 5/2+
160Eu 63 97 159.93183698(97) 1973 42.6(5) s β 160Gd (5−)
160mEu 93.0(12) keV 2018 30.8(5) s IT 160Eu (1−)
161Eu 63 98 160.933664(11) 1986 26.2(23) s β 161Gd 5/2+#
162Eu 63 99 161.9369583(14) 1987 ~10 s β 162Gd 1+#
162mEu 158.0(17) keV 2018 15.0(5) s IT 162Eu (6+)
163Eu 63 100 162.93926551(97) 2007 7.7(4) s β 163Gd 5/2+#
163mEu 964.5(5) keV 2017 911(24) ns IT 163Eu (13/2−)
164Eu 63 101 163.9428529(22) 2007 4.16(19) s β 164Gd 3−#
165Eu 63 102 164.9455401(56) 2007 2.163+0.139
−0.120
 s
[13]
β 165Gd 5/2+#
166Eu 63 103 165.94981(11)# 2012 1.277+0.100
−0.145
 s
[13]
β (99.37%) 166Gd 0−#
β, n (0.63%) 165Gd
167Eu 63 104 166.95301(43)# 2012 852+76
−54
 ms
[13]
β (98.05%) 167Gd 5/2+#
β, n (1.95%) 166Gd
168Eu 63 105 167.95786(43)# 2012 440+48
−47
 ms
[13]
β (96.05%) 168Gd 6−#
β, n (3.95%) 167Gd
169Eu 63 106 168.96172(54)# 2018 389+92
−88
 ms
[13]
β (85.38%) 169Gd 5/2+#
β, n (14.62%) 168Gd
170Eu 63 107 169.96687(54)# 2022 197+74
−71
 ms
[13]
β (>76%) 170Gd
β, n (<24%) 169Gd
This table header & footer:
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  1. mEu  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life  nearly stable, half-life longer than age of universe.
  5. #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  6. Bold italics symbol as daughter  Daughter product is nearly stable.
  7. Bold symbol as daughter  Daughter product is stable.
  8. () spin value  Indicates spin with weak assignment arguments.
  9. Order of ground state and isomer is uncertain.
  10. Believed to undergo α decay to 149Pm with a half-life over 5.5×1017 years

Europium-155

More information Nuclide, t1⁄2 ...
Nuclide t12 Yield Q[a 1] βγ
(a) (%)[a 2] (keV)
155Eu 4.740.0803[a 3]252 βγ
85Kr 10.730.2180[a 4]687 βγ
113mCd 13.90.0008[a 3]316 β
90Sr 28.914.5052826[a 5] β
137Cs 30.046.3371176 βγ
121mSn 43.90.00005390 βγ
151Sm 94.60.5314[a 3]77 β
  1. Decay energy is split among β, neutrino, and γ if any.
  2. Per 65 thermal neutron fissions of 235U and 35 of 239Pu.
  3. Neutron poison; in thermal reactors, most is destroyed by further neutron capture.
  4. Less than 1/4 of mass-85 fission products as most bypass ground state: 85Br → 85mKr → 85Rb.
  5. Has decay energy 546 keV; its decay product 90Y has decay energy 2.28 MeV with weak gamma branching.
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Europium-155 is a fission product with a half-life of 4.742 years and has a maximum decay energy of 252 keV. Because of its position on the high-mass end of the yield curve, it has a low fission product yield, about 1 to 2% that of the most abundant fission products.

155Eu's large neutron capture cross section means that most of the small amount produced is destroyed in the course of the nuclear fuel's burnup. Yield, decay energy, and half-life are all far less than that of 137Cs and 90Sr, so 155Eu is not a significant contributor to nuclear waste.

Some 155Eu is also produced by successive neutron captures on 153Eu and 154Eu, whose direct fission yield is extremely small as its mass chain stops at 154Sm. However, the high cross sections, and even higher for 155 than 154, mean that both 155Eu and 154Eu are destroyed faster than they are produced. See the table below for numeric details on this process.

More information Isotope, Half-life ...
IsotopeHalf-lifeRelative yield (fission)Thermal neutronResonance integral
Eu-153Stable53501500
Eu-1548.592 years~015001600
Eu-1554.742 years1390016000
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See also

References

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