Talk:Wave function/Archive 3
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Complex valued function?
"Typically, its values are complex numbers and, for a single particle, it is a function of space and time."
Is this true of any but a scalar particle? I know I'll probably spark a debate because this is not my area, but surely this is oversimplification to the point of confusion? For example, I'd expect any fermion to have a wavefunction that is spinor-valued, in which case complex numbers might come into it, depending on the representation chosen, but also might not. Shouldn't this description be changed? —Quondum 21:48, 15 March 2014 (UTC)
- Yes, in general a spinor,or other things I don't know about, but we need to start from somewhere, and the first introduction to wavefunctions is always through complex numbers as far as I know. Presumably your'e thinking of multivector-valued wavefunctions in geometric algebra which have the "spinorial" behavior (according to Hestenes' use of the term "spinor")? For now, probably best left as complex numbers with a pointer saying other quantities are occur, maybe have a section on this too. M∧Ŝc2ħεИτlk 08:58, 16 March 2014 (UTC)
- This, being an encyclopaedia and not a textbook, has rather strict guidelines about how it can present things. As such, the lead completely violates the guidelines. Even if one chose to take a pedagogical approach in the body of the text, I would have considered it necessary to make it clear that the approach is not the general one, and also to omit the invalid simplification from the lead. For example, one could say "Typically, for a single particle, it is a function of space and time."
- I was thinking of spinors of any representation, be they Dirac's complexified vectors or either of the two most suitable GA representations, neither of which is an algebra over the complex numbers. From all perspectives (pedagogic and encyclopaedic), I think that it is important to maintain a clear distinction between what is being represented and the representation. I see the confusion in thinking that extends quite high (to some postgrads) when they use only one representation because they fail to disentangle these, for example with tensors and the Ricci calculus, where people are taught in effect that the collection of components is a tensor, and that the definition of a tensor is a set of components that transforms appropriately. Especially pedagogically, I feel that this is highly counterproductive because people are being taught the "arithmetic" of QM while glossing over its "mathematics", and encyclopaedically it is just plain wrong. —Quondum 16:05, 16 March 2014 (UTC)
- Representation of what? Schrödingerian mechanics isn’t Lorentz/Poincaré invariant. It is Galilean-invariant. Usually, things that are Lorentz/Poincaré invariant are not called wave functions. These are fermionic fields and so. Incnis Mrsi (talk) 17:22, 16 March 2014 (UTC)
- I can see this bogging down in undefined terminology. Would you care to put that statement ("things that are Lorentz/Poincaré invariant are not called wave functions") into the article? If true, it would certainly be helpful. Also, is the concept restricted to scalar particles? It would also help if this were made clear in the article. Coming from an outside perspective, I cannot even determine what the term wavefunction covers, and what it doesn't cover. With regard to representation, a particle is not a complex function of space and time, but it could be represented by a complex function. Or is the wavefunction by definition the complex value representation of a particle? The article seems to leave all these questions unanswered. —Quondum 06:03, 17 March 2014 (UTC)
- Physics bogged down in terminology for a long time, but this is your “represented” verb that is undefined here. When I read about representations, I thought we talk about representation theory of symmetry groups. No, I won’t put the Lorentz/Poincaré invariance speculation into the article. The relativistic quantum mechanics uses hyperbolic (Lorentz-covariant) Hamiltonians with wave functions. Also, Wikipedia states:
Nevertheless, RQM is only an approximation to a fully self-consistent relativistic theory of known particle interactions because it does not describe cases where the number of particles changes; for example in matter creation and annihilation.
- If you replace QM with wave function, then it will be consistent with my understanding. When you know how many (and which) particles do you have, then you have a wave function. When you don’t know it, then you have a field. Also, you can read here on a thought experiment that shows that “how many and which particles” concept is blurry, and it is related to your spinors. You can speak about spinor-valued wave functions only if you have some kind of Spin(3) symmetry. If you haven’t, then values are merely complex (finite-dimensional) vectors that represent some opaque states of the system. Yes, a particle, or a system of particles, is not obliged to have only one internal state. Incnis Mrsi (talk) 07:40, 17 March 2014 (UTC)
- My use of the term representation is clearly confusing the matter, so let's drop the term. Whether we are dealing with (non-R)QM or RQM does not seem to be significant to the concept of a wavefunction. I agree that the concept of a wavefunction does not really apply to QFT. From what you say, you appear to consider solutions the single-particle Dirac equation as wavefunctions in the sense of the article, even if regarded as complex vector fields. This alone is enough to suggest that the description "its values are complex numbers" in the lead should be made more general. I'm suggesting that in the lead it should rather say something like "It is generally vector-valued and, for a single particle, it is a function of space and time." Or even simply "For a single particle, it is a function of space and time." The discussion of whether the vectors are considered to be over complex numbers or to be elements of a Clifford algebra need not be addressed in the lead. Scalar particles are simply a special case of vectors. —Quondum 18:40, 17 March 2014 (UTC)
- Physics bogged down in terminology for a long time, but this is your “represented” verb that is undefined here. When I read about representations, I thought we talk about representation theory of symmetry groups. No, I won’t put the Lorentz/Poincaré invariance speculation into the article. The relativistic quantum mechanics uses hyperbolic (Lorentz-covariant) Hamiltonians with wave functions. Also, Wikipedia states:
- I can see this bogging down in undefined terminology. Would you care to put that statement ("things that are Lorentz/Poincaré invariant are not called wave functions") into the article? If true, it would certainly be helpful. Also, is the concept restricted to scalar particles? It would also help if this were made clear in the article. Coming from an outside perspective, I cannot even determine what the term wavefunction covers, and what it doesn't cover. With regard to representation, a particle is not a complex function of space and time, but it could be represented by a complex function. Or is the wavefunction by definition the complex value representation of a particle? The article seems to leave all these questions unanswered. —Quondum 06:03, 17 March 2014 (UTC)
- Representation of what? Schrödingerian mechanics isn’t Lorentz/Poincaré invariant. It is Galilean-invariant. Usually, things that are Lorentz/Poincaré invariant are not called wave functions. These are fermionic fields and so. Incnis Mrsi (talk) 17:22, 16 March 2014 (UTC)
Quondum, you refer to WP policies. One of the most important is to write from what most sources say: of course not like a textbook but as a plain English summary. Well, does anyone know how many introductory QM sources which do not use write wavefunctions as complex numbers or complex-valued vectors? Complex numbers are exclusively used in almost every single introductory QM book I've ever seen (anyone is welcome to contradict with examples). The only exception I can think of is when QM is written in the language of geometric algebra, which uses the field of real numbers. The restricted scope "introductory QM" is not meant to be pedagogic - this is one important level of sources we should use for this article.
As for:
- "With regard to representation, a particle is not a complex function of space and time, but it could be represented by a complex function. Or is the wavefunction by definition the complex value representation of a particle? The article seems to leave all these questions unanswered"
the article has an ontology section linking to the main ontology article - saying the meaning of the wavefunction is unclear, and always has been from day 1. The sections on wavefunctions for one particle in 1d, and more particles in higher dimensions, all mention the Copenhagen interpretation, the most introductory interpretation of the wavefunction.
It's a bit unfair to say the lead totally violates the guidelines. It can be improved, but it gets the main points across. I'm not denying the article still needs work. But this discussion confuses me. M∧Ŝc2ħεИτlk 16:40, 22 March 2014 (UTC)
- A sensible definition of what a wave function is might be that it solves a wave equation. This holds true in all cases I can think of. What a wave equation is is well defined as far as I know.
- It is not true that wave functions aren't present in QFT. They are necessary to construct the Hilbert space. (Any complete set will do.) They just don't occupy the center of the stage; the dynamics (time evolution of the system) is moved to the operators on the Hilbert space. In addition, new operators are introduced to handle creation and destruction of particles. YohanN7 (talk) 23:40, 22 March 2014 (UTC)
- QFT is beyond scope. I said nothing about the interpretation. I have evidently failed to communicate my point about the space from which the wave function may take its values (codomain), without which my comment about guidelines is also meaningless. I see little point in pursuing this. —Quondum 00:27, 23 March 2014 (UTC)
- Quondum and YohanN7 - I was still thinking we could describe the role of the wavefunction in non-RQM, RQM, and QFT, all in a section for comparison. In all this time it just hasn't been done. Currently the article biases the Schrödinger picture. As I mentioned above, we could have a brief section on how operators act on the wavefunction in the Schrödinger picture (and related, briefly mention how statistical quantities like averages can be found), then go onto the Heisenberg picture, and possibly the interaction picture, again all in a section for comparison. No, we will not turn the article into a second Dynamical pictures (quantum mechanics), just an overview.
- Quondum, no, you've raised a good point. There is a bias with complex numbers, sure, and having a variety of mathematical languages would remove the bias. Since you raised the point, others will probably ask the same question. I'm simply not sure how to do this yet.
- Thanks. (P.S. YohanN7 sorry about not checking in Griffiths yet, I couldn't find it last week). M∧Ŝc2ħεИτlk 07:54, 23 March 2014 (UTC)
- Wave functions take their values in Cn for n ≥ 1, and this covers the rare cases (e.g Majorana fermions, and certain potentials in one dimension (forgot details, see Landau and Lifshits)) when they can be taken as real-valued. Why talk about guidelines? I can't honestly see the point in having a huge debate about this. The GA representations are clearly fringe (unless something revolutionary has happened the last few years), so they can be left out. YohanN7 (talk) 09:40, 23 March 2014 (UTC)
- This isn't just about guidelines, it's about content.
- If it helps, I saved up enough to order Wienberg's vol 1 Quantum theory of fields, Landau and Lifshitz's vol 2 Classical theory of fields, and Doran and Lasenby's Geometric algebra for physicists (which includes QM formulated using geometric algebra). All fairly expensive, but there is no way round that, and they're top quality books so it's just about tolerable. Next week it will be the easter break too. Within the next week the books hopefully arrive and I get more time, it will be easier to make edits. M∧Ŝc2ħεИτlk 10:03, 23 March 2014 (UTC)
- Excellent choices. The L&L book also covers general relativity (guess you knew this, much much better than MTW). YohanN7 (talk) 10:20, 23 March 2014 (UTC)
- You might want to have a look at Field Quantization by Walter Greiner et al. Weinbergs attitude is that he doesn't quantize any pre-existing theory. But is quite useful to see that view too. It contains hundreds of detailed calculations, and it has a highly unusual description of classical field theory (Poisson-bracket formulation). Only $20 at amazon. YohanN7 (talk) 12:46, 23 March 2014 (UTC)
- Greiner's books are OK (the classical mechanics, QM, RQM, QED, QCD, and Field quantization (if I recall correctly) are all at the library). But for now Weinberg's first volume is enough. Thanks for the suggestion. Yes, while MTW is a well-known and widely used classic, some bits are inadequate (e.g. the angular momentum sections are a bit vague, the relativistic heat conduction is not thorough, and there doesn't seem to be any description of the relativistic D, H, M, P fields in matter, all these are remedied either by Pauli or Tolman). LL's classical theory of fields seems to be loaded: SR, EM, GR using Lagrangian mechanics and field theory. M∧Ŝc2ħεИτlk 14:11, 23 March 2014 (UTC)
- Mentioning that Cn may be the space is reasonable, mainly just not implying a limitation to C. No need (and it may be unwise especially in the lede) to mention GA or any specific space (vectors, matrices etc.), but preferably don't imply their exclusion by the wording. And forget my mention of guidelines: I was hoping to aid understanding of rather than to push my point. And my point does not imply any effort in adding detail about spaces, only wording that does not create misconceptions. We know that isomorphisms exist; we don't need them to be enumerated. —Quondum 16:33, 23 March 2014 (UTC)
I'll have a very quick go at tweaking the lead along these lines. M∧Ŝc2ħεИτlk 16:56, 23 March 2014 (UTC)
- Not so quick, please. First, wave mechanics is a dab page. Second, although it is true that a particle with spin has a spinor-valued wave function, I’d not assert that a spinless particle is always scalar. Which spin has a (non-rotating) ammonia molecule? With 14
7N1
1H3 it certainly isn’t zero (even number of electrons and odd number of nucleons), but I do not see a reason for it not to be spinless with an appropriate isotope composition. So, is it a scalar particle, is it really? Incnis Mrsi (talk) 18:24, 23 March 2014 (UTC)
- Thank you: your edit is a massive improvement, and makes the lede both understandable and essentially complete in its description. —Quondum 18:10, 23 March 2014 (UTC)
Relation between wave functions
I tried to explain a little. There are probably bugs in the new equations, possibly a missing minus sign (the plane wave), and possible a missing factor of one over two pi (delta function normalization). These things depend on conventions, including for the Fourier transform. Can anyone check what Griffith (the ref in the section) says? YohanN7 (talk) 22:47, 15 March 2014 (UTC)
- Nice work. Except for one quibble: we now have the inner product of momentum states before the concepts of the inner product is introduced even in the position representation, so these should be moved down into the inner product section. I don't have Griffith's QM book now but may be able to check sometime in the week. M∧Ŝc2ħεИτlk 08:58, 16 March 2014 (UTC)
- I have noticed the mentioned quibble. Will make an attempt later today to fix it. YohanN7 (talk) 10:33, 16 March 2014 (UTC)
- Oops, I missed the time dependence. But, should we instead state that it is the solution of the time-independent Schrödinger equation? Time dependence is mostly disturbing in this section. YohanN7 (talk) 03:22, 24 March 2014 (UTC)
Hydrogen wave animation
May I destroy ? This flickering picture that does not, actually, “animate” anything useful, only distracts attention and wastes the processor time. Incnis Mrsi (talk) 13:36, 29 March 2014 (UTC)
- It does not add anything; it is merely an attempt at a different presentation of what is already there. From the description "hydrogen wave animation" I had expected the evolution of a wavefunction in time, but it is nothing of the sort. I agree with Incnis that it should be removed. —Quondum 16:10, 29 March 2014 (UTC)
Limited by the speed of light?
I'm not a quantum mechanic (can't handle those teeny, tiny wrenches) so forgive me if I'm not putting this question correctly, but I wonder if someone could say (and maybe put in the article) something about how causality and the speed of light relate to the time-dependent wavefunction. I assume the wavefunction is causal? If the boundary conditions or the potential are altered in one place, do the resulting changes in the wavefunction propagate to other places at the speed of light? And what about the delayed quantum eraser experiment? Thanks. --ChetvornoTALK 06:38, 27 October 2013 (UTC)
- An interesting question.
- Quantum entanglement itself does not violate special relativity because information is not transmitted "in" the wavefunction. For two observers to agree on the outcome of an experiment, one observer has to send a signal to the other, which is limited by c. For time-dependent potentials, presumably there would be time-dependent phase factors in the wavefunction related to the potential, like the Aharonov–Bohm effect.
- In any case it would be a good addition to the article, thanks for raising this, will look into it. M∧Ŝc2ħεИτlk 07:03, 27 October 2013 (UTC)
- In non-relativistic QM causality isn't a problem, while the speed of light certainly is a problem. In relativistic QFT, this can dealt with using the cluster decomposition principle, which is weaker (I believe) than a strict causality requirement, but has the advantage that one need not care about whether fields are measurable in any sense. This principle (roughly) implies that quantum fields commute at space-like distances, in turn yielding relativistic field equations, both for states and field operators. YohanN7 (talk) 17:12, 3 April 2014 (UTC)