1,2-Bis(diphenylphosphino)benzene

Chemical compound From Wikipedia, the free encyclopedia

1,2-Bis(diphenylphosphino)benzene (dppbz) is an organophosphorus compound with the formula C6H4(PPh2)2 (Ph = C6H5). Classified as a diphosphine ligand, it is a common bidentate ligand in coordination chemistry.[1] It is a white, air-stable solid. [2] As a chelating ligand, dppbz is very similar to 1,2-bis(diphenylphosphino)ethylene.

Quick facts Names, Identifiers ...
1,2-Bis(diphenylphosphino)benzene
Names
Preferred IUPAC name
(1,2-Phenylene)bis(diphenylphosphane)
Other names
o-Phenylenebis[diphenylphosphine, dppben, dppbenz, dppbe, dppBz, dppbz
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C30H24P2/c1-5-15-25(16-6-1)31(26-17-7-2-8-18-26)29-23-13-14-24-30(29)32(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-24H
    Key: NFRYVRNCDXULEX-UHFFFAOYSA-N
  • C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5
Properties
C30H24P2
Molar mass 446.470 g·mol−1
Appearance white solid
Melting point 185–187 Â°C (365–369 Â°F; 458–460 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 Â°C [77 Â°F], 100 kPa).
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