1,2-Diiodoethane

Chemical compound From Wikipedia, the free encyclopedia

1,2-Diiodoethane is an organoiodine compound.[1]

Quick facts Names, Identifiers ...
1,2-Diiodoethane
Skeletal formula of 1,2-diiodoethane
Skeletal formula of 1,2-diiodoethane
Stick and Balls model of 1,2-diiodoethane
Stick and Balls model of 1,2-diiodoethane
Tube model of 1,2-diiodoethane
Tube model of 1,2-diiodoethane
Space Filling model of 1,2-diiodoethane
Space Filling model of 1,2-diiodoethane
Names
Preferred IUPAC name
1,2-Diiodoethane
Other names
Ethylene iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.009.872 Edit this at Wikidata
UNII
  • InChI=1S/C2H4I2/c3-1-2-4/h1-2H2
    Key: GBBZLMLLFVFKJM-UHFFFAOYSA-N
  • InChI=1/C2H4I2/c3-1-2-4/h1-2H2
    Key: GBBZLMLLFVFKJM-UHFFFAOYAR
  • ICCI
Properties
C2H4I2
Molar mass 281.863 g·mol−1
Density 2.13 g/cm3
Melting point 80 to 82 Â°C (176 to 180 Â°F; 353 to 355 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 Â°C [77 Â°F], 100 kPa).
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Preparation and reactions

1,2-Diiodoethane can be prepared by the reaction of ethylene with iodine (I2):[2]

C2H4 + I2 ⇌ C2H4I2

1,2-Diiodoethane is most commonly used in organic synthesis in the preparation of samarium(II) iodide or ytterbium(II) iodide in an inert solvent such as THF.[3]

Sm + ICH2CH2I → SmI2 + H2C=CH2

Spectral properties

In mass spectroscopy, 1,2-diiodoethane exhibits 5 major peaks, with the base peak showing at 155 m/z, which is the loss of one iodine atom (127 m/z).

References

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