1,3-Diphenyltriazene

Chemical compound From Wikipedia, the free encyclopedia

1,3-Diphenyltriazene is the organic compound with the formula PhN=N-N(H)Ph (Ph = C6H5). It is a prototypical triazene, i.e. a compound with the functional group RN=N-NR2. It is a pale yellow solid, prepared by the reaction of phenyldiazonium chloride with aniline.[3] It can be prepared from aniline in a one-pot reaction via partial diazotization.[4][5] It is a planar molecule. The N-N distances are 1.287 and 1.337 Å.[6]

Quick facts Names, Identifiers ...
1,3-Diphenyltriazene
Names
Preferred IUPAC name
1,3-Diphenyltriaz-1-ene
Other names
Diazoaminobenzene
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.004.764 Edit this at Wikidata
EC Number
  • 205-240-1
UNII
  • InChI=1S/C12H11N3/c1-3-7-11(8-4-1)13-15-14-12-9-5-2-6-10-12/h1-10H,(H,13,14)
    Key: ALIFPGGMJDWMJH-UHFFFAOYSA-N
  • C1=CC=C(C=C1)NN=NC2=CC=CC=C2
Properties
C12H11N3
Molar mass 197.241 g·mol−1
Appearance Pale yellow solid
Density 1.29 g/cm3
Melting point 95–96[1] Â°C (203–205 Â°F; 368–369 K)
Boiling point 180 Â°C (356 Â°F; 453 K) decomposes[2]
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H302, H312, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 Â°C [77 Â°F], 100 kPa).
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References

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