Alizarin cyanine R

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Alizarin cyanine R
Names
IUPAC name
1,2,4,5,7,8-Hexahydroxyanthraquinone
Other names
  • Alizarine Cyclamine R
  • 1,2,4,5,7,8-Hexahydroxy-9,10-anthracenedione
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/C14H8O8/c15-3-1-5(17)11(19)9-7(3)13(21)8-4(16)2-6(18)12(20)10(8)14(9)22/h1-2,15-20H
    Key: NEVTZWLESVDYDA-UHFFFAOYSA-N
  • C1=C(C2=C(C(=C1O)O)C(=O)C3=C(C2=O)C(=CC(=C3O)O)O)O
Properties
C14H8O8
Molar mass 304.022 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Alizarin cyanine R is an anthraquinone dye and belongs to the mordant dyes[1]

Alizarin cyanine R was discovered by R. E. Schmidt in 1891.[1]

Representation

Alizarin cyanine R can be obtained by oxidation of alizarin Bordeaux with manganese dioxide, analogous to the oxidation of alizarin to purpurin.[2]

Another route involves Chinalizarin (C.I. 58500), which is treated with manganese dioxide in sulfuric acid, followed by oxidation of the resulting quinone and subsequent reduction (chemistry) with sulfurous acid.[1]

A further possibility is the oxidation of anthrapurpurin (C.I. 58255) with Oleum.[1]

Use

Differentiation from C.I. Mordant Blue 32

References

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