Argentium sterling silver
Brand of tarnish-resistant silver alloys
From Wikipedia, the free encyclopedia
Argentium silver (patented in 1998)[1] is a brand of modern tarnish-resistant silver alloys, containing either 93.5%, 94% or 96% silver. Argentium alloys replace some of the copper in the traditional sterling silver (92.5% silver + 7.5% copper) with the metalloid germanium.[a][1][2] Argentium 935, Argentium 940 and Argentium 960 alloys exceed the standard required for hallmarking as sterling silver, and Argentium 960 silver meets the standard for hallmarking as Britannia silver (95.84% silver).
Origins and description
Argentium silver is the result of research at the Art and Design Research Institute (ADRI), School of Art & Design, Middlesex University, by Peter Johns and colleagues. The project began in 1990 with research on the effects of germanium additions to silver alloys. Germanium was discovered to impart the following properties to sterling silver:[3]
- firescale elimination
- high tarnish resistance[4]
- precipitation hardening and simple heat-hardening properties[5]
- increased ductility
- increased thermal and electrical resistivity[b]
- environmental advantages[c]
Many of these properties significantly affect the traditional methods of working silver. For instance the absence of firescale eliminates tedious and time-consuming steps required by the silver worker using traditional sterling silver. It also eliminates the need for plating the final product which is often done on manufactured items because of the problems introduced by firescale. Tarnish resistance is of significant importance to both silver workers and the wearer of silver jewellery.
In 1994, Peter Johns sought and received U.S. utility patent protection for argentium silver, although both the metal and methods for making it became part of the public domain on August 27, 2016 when the patent expired and patent protection thereby ceased.[1]
Via various corporate entities, Johns also sought U.S. trademark protection for the word “argentium,” though his trademark was canceled by the federal government in June 2014 based on a failure to provide evidence of a valid trademark under Section 8 of the Lanham Act.[6] Eventually, Johns filed a new application attempting to trademark only the word “argentium” when used with a limited subset of enumerated goods and services.[7]. However, that trademark may also be invalid under the Supreme Court’s “utilitarian functionality” doctrine, which renders a trademark presumptively invalid if it covers the same subject matter as “an expired utility patent.” TrafFix Devices, Inc. v. Marketing Displays, Inc., 532 U.S. 23 (2001). Since argentium was already covered by Johns’ now-expired utility patent, his trademark purporting to cover the same metal is presumptively invalid. See Id. As of April 2026, no court has ever found the “argentium” trademark to be valid.
Physical properties
Refractory temperatures Silver
alloySolidus
melting
temperatureLiquidus
flow point
temperature°C °F °C °F traditional
sterling silver802 °C 1475 °F 899 °C 1650 °F argentium
940860 °C 1580 °F 895 °C 1643 °F argentium
960890 °C 1634 °F 920 °C 1688 °F
Footnotes
- Increased resistance improves alloys' suitability for welding and laser forming.
- The "environmental" advantages result from eliminating the need for harsh chemicals involved in removing or plating over firescale.