Athabascaite
From Wikipedia, the free encyclopedia
| Athabascaite | |
|---|---|
| General | |
| Category | Selenide mineral |
| Formula | Cu5Se4 |
| IMA symbol | Atb[1] |
| Strunz classification | 2.BA.15d |
| Crystal system | Orthorhombic Unknown space group |
| Unit cell | a = 8.227 Å, b = 11.982 Å c = 6.441 Å; Z = 4 |
| Identification | |
| Color | Light grey, bluish-gray to white |
| Crystal habit | As anhedral inclusions and lath shaped crystals, also massive |
| Mohs scale hardness | 2.5 |
| Luster | Metallic |
| Diaphaneity | Opaque |
| Specific gravity | 6.59 (calculated) |
| Optical properties | Anisotropism strong, creamy white to dark blue |
| Pleochroism | Distinct, pale gray to blue-gray |
| References | [2][3][4] |
Athabascaite is a member of the copper selenide minerals, and forms with other copper selenides. It was first discovered by S. Kaiman in 1949 while he was researching radioactive materials around Lake Athabasca. Kaiman was conducting research near Uranium City, Saskatchewan where mass amounts of uranium mines were present.[5]
Kaiman sent his specimens for testing to J. W. Earley, then a graduate student. With the invention of the microprobe analyzer, D.C. Harris decided to delve further into the virtually unknown mineral with little success.[6]
Structure
Because of unavailability of sufficiently large single crystals, little is known about the atomic structure of athabascaite. Copper (Cu+) serves as the cations, selenium (Se2−) serves as the anions, and the two are joined by ionic bonds. The crystal symmetry appears orthorhombic with the lattice parameters a = 8.227 ± 0.01, b = 11.982 ± 0.02, and c = 6.441 ± 0.01 Å. It has a calculated density of 6.59 g/cm3; this density is identical to that of umangite, and therefore the two are thought to have similar structure.[5]