Athabascaite

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Athabascaite
General
CategorySelenide mineral
FormulaCu5Se4
IMA symbolAtb[1]
Strunz classification2.BA.15d
Crystal systemOrthorhombic
Unknown space group
Unit cella = 8.227 Å, b = 11.982 Å
c = 6.441 Å; Z = 4
Identification
ColorLight grey, bluish-gray to white
Crystal habitAs anhedral inclusions and lath shaped crystals, also massive
Mohs scale hardness2.5
LusterMetallic
DiaphaneityOpaque
Specific gravity6.59 (calculated)
Optical propertiesAnisotropism strong, creamy white to dark blue
PleochroismDistinct, pale gray to blue-gray
References[2][3][4]

Athabascaite is a member of the copper selenide minerals, and forms with other copper selenides. It was first discovered by S. Kaiman in 1949 while he was researching radioactive materials around Lake Athabasca. Kaiman was conducting research near Uranium City, Saskatchewan where mass amounts of uranium mines were present.[5]

Kaiman sent his specimens for testing to J. W. Earley, then a graduate student. With the invention of the microprobe analyzer, D.C. Harris decided to delve further into the virtually unknown mineral with little success.[6]

Structure

Because of unavailability of sufficiently large single crystals, little is known about the atomic structure of athabascaite. Copper (Cu+) serves as the cations, selenium (Se2−) serves as the anions, and the two are joined by ionic bonds. The crystal symmetry appears orthorhombic with the lattice parameters a = 8.227 ± 0.01, b = 11.982 ± 0.02, and c = 6.441 ± 0.01 Å. It has a calculated density of 6.59 g/cm3; this density is identical to that of umangite, and therefore the two are thought to have similar structure.[5]

Physical properties

Geologic occurrence

References

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