Bis(triphenylphosphine)iron tricarbonyl

Bis(triphenylphosphine)iron tricarbonyl
Identifiers
CAS Number	21255-52-7;
3D model (JSmol)	Interactive image;
ChemSpider	4807608;
PubChem CID	6097100;
	InChI InChI=1S/2C18H15P.3CO.Fe/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;31-2;/h2*1-15H;;;; Key: NPCXYZUUVGQEGS-UHFFFAOYSA-N;
	SMILES [C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Fe];
Properties
Chemical formula	C39H30FeO3P2
Molar mass	664.459 g·mol−1
Appearance	yellow solid
Melting point	262–266 °C (504–511 °F; 535–539 K) decomp
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Tricarbonylbis(triphenylphosphine)iron(0) is a coordination complex with the formula Fe(CO)₃(PPh₃)₂ (Ph = C₆H₅). A yellow solid, this complex is derived from iron pentacarbonyl by replacement of two carbonyl ligands by triphenylphosphine (PPh₃).

References

Identifiers

CAS Number	21255-52-7
3D model (JSmol)	Interactive image
ChemSpider	4807608
PubChem CID	6097100
InChI InChI=1S/2C18H15P.3CO.Fe/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;31-2;/h2*1-15H;;;; Key: NPCXYZUUVGQEGS-UHFFFAOYSA-N
SMILES [C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Fe]
Properties
Chemical formula	C₃₉H₃₀FeO₃P₂
Molar mass	664.459 g·mol⁻¹
Appearance	yellow solid
Melting point	262–266 °C (504–511 °F; 535–539 K) decomp
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references