Bismoclite
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| Bismoclite | |
|---|---|
Yellow-orange bismoclite interspersed with bismuthinite from the Alto do Giz pegmatite, Equador, Rio Grande do Norte, NE-region, Brazil. Approximate image width: 5 mm. | |
| General | |
| Category | Halide mineral |
| Formula | BiOCl |
| IMA symbol | Bmc[1] |
| Strunz classification | 3.DC.25 |
| Dana classification | 10.2.1.2 |
| Crystal system | Tetragonal |
| Crystal class | Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m) |
| Space group | P4/nmm |
| Unit cell | a = 3.887 Å, c = 7.354 Å; Z = 2 |
| Identification | |
| Color | Cream-white, greyish, yellowish brown |
| Crystal habit | Platey to thin rectangular crystals, fibrous to columnar, massive |
| Cleavage | {001} perfect |
| Tenacity | Elastic |
| Mohs scale hardness | 2-2.5 |
| Luster | Greasy, silky, pearly, dull, earthy |
| Streak | White |
| Diaphaneity | Transparent to translucent |
| Specific gravity | 7.36 (measured), 7.784 (calculated) |
| Optical properties | Uniaxial (-) |
| Refractive index | nω = 2.150 nε = 1.910 |
| Birefringence | δ = 0.240 |
| References | [2][3][4][5] |
Bismoclite is a bismuth oxohalide mineral with formula BiOCl. It is the naturally occurring form of bismuth oxychloride. The name was derived from its chemical constituents. It is a secondary bismuth mineral first thought to be composed of bismuthyl ions (BiO+) and chloride anions, however, the existence of the diatomic bismuthyl ion is doubtful.[6]
It is a member of the matlockite group.
It was first described in 1935 from alluvium near bismuth-bearing pegmatites in South Africa.[3] It has been found in association with granite pegmatite and in greisen. Associated minerals include bismutite, mica, jarosite, alunite, cerussite, atacamite, connellite. Occurrences include the type locality at Jackals Water, SW of Prieska, South Africa; Bygoo, Australia; the Tintic district in the East Tintic Mountains of Utah; and from Dalbeattie, Scotland.[4]