Carbokentbrooksite

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Formula(Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O (original form)
Strunz classification9.CO.10 (10 ed)
8/E.25-32 (8 ed)
Carbokentbrooksite
General
CategorySilicate mineral, Cyclosilicate
Formula(Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O (original form)
IMA symbolCktb[1]
Strunz classification9.CO.10 (10 ed)
8/E.25-32 (8 ed)
Dana classification64.1.2.3
Crystal systemTrigonal
Crystal classDitrigonal pyramidal (3m)
(same H-M symbol)
Space groupR3m
Unit cella = 14.24, c = 30.04 [Å]; Z = 3
Identification
ColorYellow, yellow-orange
Crystal habitrhombohedra (cores of zoned crystals)
CleavageNone
FractureConchoidal
TenacityBrittle
Mohs scale hardness5
LusterVitreous
StreakWhite
DiaphaneityTransparent
Density3.14 (measured)
Optical propertiesUniaxial (−)
Refractive indexnω = 1.65, nε = 1.64 (approximated)
PleochroismNone
Ultraviolet fluorescenceNo
References[2][3]

Carbokentbrooksite is a very rare mineral of the eudialyte group,[2] with formula (Na,)12(Na,Ce)3Ca6Mn3Zr3NbSiO(Si9O27)2(Si3O9)2(OH)3(CO3).H2O.[3] The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group.[4] Carbokenbrooksite characterizes in being carbonate-rich (the other eudialyte-group species with essential carbonate are zirsilite-(Ce), golyshevite, and mogovidite). It is also sodium rich, being sodium equivalent of zirsilite-(Ce),[2] with which it is intimately associated.[3]

Carbokentbrooksite and zirsilite-(Ce) are found as replacements of grains and crystals of eudialyte.[2] They occur in pegmatites of Darai-Pioz alkaline massif, Tajikistan – a locality known for many rare minerals.[5] The minerals are associated with aegirine, ekanite, microcline, polylithionite, quartz, stillwellite-(Ce) (silicates), pyrochlore-group mineral, fluorite, calcite, and galena.[3]

Notes on chemistry

Notes on structure

References

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