Chatoyancy

Optical reflectance effect in materials From Wikipedia, the free encyclopedia

In gemology, chatoyancy (/ʃəˈtɔɪ.ənsi/ shə-TOY-ən-see), also called chatoyance or the cat's-eye effect,[1] is an optical phenomenon in which a narrow, luminous band of reflected light appears across the surface of certain gemstones. The band resembles the slit pupil of a cat's eye and appears to glide across the surface as the stone, the light source, or the observer moves. The same terminology is used also in wood science to describe the phenomenon happening in some valuable wood species, like genuine mahoganies, khaya, sapele, sipo etc.[2]

Tiger's eye
A tropical veneer exhibiting a very high chatoyancy
Tiger's eye

The term derives from the French œil de chat ("cat's eye"). Although historically used primarily in gemology, analogous optical effects occur in other fibrous or anisotropic materials, including wood, where they are commonly described as a special wood figure, or even chatoyance.

Chatoyancy results from the directional reflection of light by parallel fibrous structures or aligned needle-like inclusions within a material. In tiger's eye, the effect is produced by parallel fibrous crystals, whereas in cat's-eye chrysoberyl it is caused by parallel microscopic inclusions or hollow tubes, commonly composed of or associated with rutile (titanium dioxide).[3][4]

Description

Chatoyancy in the gemstone chrysoberyl is induced by the presence of the mineral rutile, a mineral primarily composed of titanium dioxide. These rutile precipitates align perpendicularly, contributing to the cat's eye effect.[5] This alignment is attributed to the rutile's lattice parameter, which matches only one of the three orthorhombic crystal axes of chrysoberyl, leading to its preferred orientation in that direction.

Optimal presentation of effect

A cabochon yellow-green quartz showing the cat's-eye effect.

To bring out the chatoyancy effect, gemstones are typically fashioned into a cabochon cut, characterized by a rounded, flat base rather than facets, with the fibrous structures aligned parallel to the base. High-quality specimens display a single, sharply defined band of light that moves across the stone when rotated, while lower-quality stones may show a banded effect similar to cat's-eye quartz. Faceted stones do not showcase the effect well.

Varieties of chatoyant materials

Gem species known for this phenomenon include quartz, chrysoberyl, beryl (especially aquamarine varieties), charoite, tourmaline, labradorite, selenite, feldspar, apatite, moonstone, thomsonite and scapolite amongst others. Chatoyancy is not limited to gemstones but can also be found in wood and carbon fiber. Synthetically made gemstones with optical fibers can also have chatoyancy. These gemstones are available in a variety of vibrant colors.[citation needed]

Cat's eye terminology

Chatoyance on Tiger's Eye

When the term "cat's eye" is used to describe a gemstone by itself, it typically refers to cat's eye chrysoberyl[6][better source needed]. It can also be used as an adjective to indicate the chatoyance phenomenon in another stone, for example, cat's eye aquamarine.

In woodworking

Chatoyancy in wood occurs in various species[7] – particularly hardwoods and the various types of Nanmu woods of China and South East Asia, particularly where stresses from the weight of the growing tree result in denser patches, or where stresses cause burl or bird's eye. This 'figure', which has a striking three-dimensional appearance, is highly prized by woodworkers and their clients alike, and is featured regularly in furniture, musical instruments, and other decorative wood products. Figuring takes on a variety of forms and is referred to as flame, ribbon, tiger stripe, quilting, among other names.[8]

This effect is sometimes called wet look, since wetting wood with water often displays the chatoyancy, albeit only until the wood dries. Certain finishes cause the wood grain to become more pronounced. Oil finishes, epoxy, and shellac can strongly bring out the wet look effect. When the refractive index of the finish nearly matches that of the wood, light scattering no longer occurs at the wood surface, adding the appearance of depth to the wood's figure.

Measurement

No method to measure wood chatoyance is unanimously accepted by the scientific community. Some methods have been proposed, such as one named PZC after the names of its inventors, Pisani, Zanetta and Codoro.[9][10] This measure has been used to measure typical values for a number of wood species; some results are reported below:[11]

Veneer of African mahogany or Khaya (PZC: 23.0)
Veneer of Etimoe (PZC: 22.1)
Veneer of Iroko or Kampala (PZC: 21.8)
More information Wood (common name), PZC average ...
Wood
(common name)
PZC average
Afrormosia 14.2
Afzelia 14.1
Alder 15.0
Alder, Red 16.8
Anigre 14.4
Ash, American White 11.5
Ash, European 12.8
Ash, Olive 14.9
Beech, European 10.6
Birch 18.3
Black Locust 16.4
Bocote 11.5
Bog Oak 11.6
Bubinga 19.2
Cedar, European 7.6
Cedar, Spanish 21.3
Cerejeira 14.1
Cherry, Black 18.0
Cherry, Sweet 15.7
Chestnut, Sweet 14.4
Cypress, Mediterranean 9.3
Ebony, Macassar 11.3
Elm 14.5
Etimoe 22.1
Eucalyptus 13.9
Fir, Douglas 11.1
Fir, European Silver 10.0
Granadillo 14.3
Guarea 17.2
Ipe 11.7
Iroko 21.8
Jatoba 17.5
Khaya 23.0
Koa 26.4
Koto 12.5
Larch, European 10.9
Limba 16.1
Limba, Black 18.7
Lime, European 12.2
Louro Faia 17.4
Louro Preto 11.3
Mahogany, Honduras 21.4
Makore 21.0
Mansonia 18.0
Maple, European 14.2
Maple, Hard 16.1
Movingui 15.3
Mulberry 18.2
Oak, Red 12.2
Oak, Sessile 12.6
Obeche 11.1
Okoume 23.6
Olive 8.3
Osage Orange, Green 17.0
Ovangkol 20.0
Padouk 17.4
Pear 10.5
Pine, Swiss Stone 10.7
Pine, unspecified 13.2
Poplar 14.7
Poplar, Yellow 11.9
Purpleheart 13.7
Red Gum 12.6
Rosewood, Cocobolo 9.5
Rosewood, Indian 11.2
Rosewood, Kingwood 14.3
Rosewood, Madagascar 11.7
Rosewood, Santos 12.5
Sapele 20.7
Satinwood 13.9
Spruce, Fiemme 9.3
Sucupira hardwood 9.8
Teak 15.7
Tineo 14.7
Walnut, African 20.2
Walnut, Black 18.6
Walnut, European 17.5
Wenge 8.5
Yew 9.8
Zebrawood 19.1
Ziricote 7.0
Close

See also

References

Related Articles

Wikiwand AI