Chlorophyllide-a oxygenase

Class of enzymes From Wikipedia, the free encyclopedia

Chlorophyllide-a oxygenase (EC 1.14.13.122), chlorophyllide a oxygenase, chlorophyll-b synthase, CAO) is an enzyme with systematic name chlorophyllide-a:oxygen 7-oxidoreductase.[1][2][3][4] This enzyme catalyses the following overall chemical reaction

+ 2 NADPH
+ 2 O2
 
 
2 H+
3 H2O
Rightward reaction arrow with minor substrate(s) from top left and minor product(s) to top right
 
 
 
+ 2 NADP+
 

The oxidation reaction uses molecular oxygen with nicotinamide adenine dinucleotide phosphate (NADPH) as a cofactor.[5]

Chlorophyllide a, (R=H) is converted to chlorophyllide b, in which the methyl group show in the green box is oxidised to a formyl group.

This enzyme contains a mononuclear iron centre and is part of the biosynthetic pathway to chlorophylls.[6][7]

See also

References

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