Chromium(II) oxide

Chemical compound From Wikipedia, the free encyclopedia

Chromium(II) oxide (CrO) is an inorganic compound composed of chromium and oxygen.[1] It is a black powder that crystallises in the rock salt structure.[2]

Quick facts Names, Identifiers ...
Chromium(II) oxide
Names
IUPAC name
chromium(II) oxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Cr.O
    Key: XVOFZWCCFLVFRR-UHFFFAOYSA-N
  • O=[Cr]
Properties
CrO
Molar mass 67.996 g/mol
Appearance black
Melting point 300 °C (572 °F; 573 K) (decomposes)
Structure
cubic, cF8
Fm3m, No. 225
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Properties

It is readily oxidized by the atmosphere. CrO is basic, while CrO3 is acidic, and Cr2O3 is amphoteric.[3]

Occurrence

CrO occurs in the spectra of luminous red novae, which occur when two stars collide. It is not known why red novae are the only objects that feature this molecule; one possible explanation is an as-yet-unknown nucleosynthesis process.[4]

Preparation

Hypophosphites such as hypophosphorous acid can reduce chromium(III) oxide to chromium(II) oxide:

H3PO2 + 2 Cr2O3 → 4 CrO + H3PO4

References

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