Classical diffusion
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Classical diffusion is a key concept in fusion power and other fields where a plasma is confined by a magnetic field within a vessel. It considers collisions between ions in the plasma that causes the particles to move to different paths and eventually leave the confinement volume and strike the sides of the vessel.
The rate of diffusion carries an inverse-square proportionality with the magnetic field, i.e., D ~ 1/B2, where D is the diffusion coefficient and B is the magnetic field strength, implying that confinement times can be greatly improved with small increases in field strength. In practice, the rates suggested by classical diffusion have not been found in real-world machines, where a host of previously unknown plasma instabilities caused the particles to leave confinement at rates closer to B, not B2, as had been seen in Bohm diffusion.
The failure of classical diffusion to predict real-world plasma behavior led to a period in the 1960s known as "the doldrums" where it appeared a practical fusion reactor would be impossible. Over time, the instabilities were found and addressed, especially in the tokamak. This has led to a deeper understanding of the diffusion process, known as neoclassical transport.

Diffusion is a random walk process that can be quantified by the two key parameters: Δx, the step size, and Δt, the time interval when the walker takes a step. Thus, the diffusion coefficient is defined as D ≡ (Δx)2 / Δt. Plasma is a gas-like mixture of high-temperature particles, the electrons and ions that would normally be joined to form neutral atoms at lower temperatures. Temperature is a measure of the average velocity of particles, so high temperatures imply high speeds, and thus a plasma will quickly expand at rates that make it difficult to work with unless some form of "confinement" is applied.
At the temperatures involved in nuclear fusion, no material container can hold a plasma. The most common solution to this problem is to use a magnetic field to provide confinement, sometimes known as a "magnetic bottle". When a charged particle is placed in a magnetic field, it will orbit the field lines while continuing to move along that line with whatever initial velocity it had. This produces a helical path through space. The radius of the path is a function of the strength of the magnetic field. Since the axial velocities will have a range of values, often based on the Maxwell-Boltzmann statistics, this means the particles in the plasma will pass by others as they overtake them or are overtaken.
If one considers two such ions traveling along parallel axial paths, they can collide whenever their orbits intersect. In most geometries, this means there is a significant difference in the instantaneous velocities when they collide - one might be going "up" while the other would be going "down" in their helical paths. This causes the collisions to scatter the particles, making them random walks. Eventually, this process will cause any given ion to eventually leave the boundary of the field, and thereby escape "confinement".
In a uniform magnetic field, a particle undergoes random walk across the field lines by the step size of gyroradius ρ ≡ vth / Ω, where vth denotes the thermal velocity, and Ω ≡ qB/m, the gyrofrequency. The steps are randomized by the collisions to lose the coherence. Thus, the time step, or the decoherence time, is the inverse of the collisional frequency νc. The rate of diffusion is given by νcρ2, with the rather favorable B−2 scaling law.