Corderoite

The structure of Hg₃S₂Cl₂ was determined in the 1960s before it was found in nature.^[6] It has crankshaft chains that are crosswise linked by additional Hg²+.^{[citation needed]} The crystals are chiral (existing in two enantiomorphic forms), in space group I2₁3 (no. 199). The chloride ions form a lattice similar to a primitive cubic lattice (but with the ions slightly displaced along three-fold axes), and the sulfide ions form a similar lattice by occupying positions near the centres of the cubes of chloride ions, also on three-fold rotation axes. This gives eight chloride and eight sulfide ions per unit cell. The mercury ions are located on two-fold rotation axes that do not intersect the three-fold rotation axes. They occupy positions close to the centres of the faces of the chloride cubes, but only half of such positions are occupied, giving 12 mercury ions per unit cell. The closest neighbors of a mercury ion are two sulfide ions, at a distance of 2.422 Å, the S-Hg-S angle being 165.1°. Each sulfide ion has three mercury ions near it, with the Hg-S-Hg angles being 94.1°. The nearest neighbors of a chloride ion are six mercury ions, at two somewhat different distances. A diagram can be seen on line, with blue balls representing mercury, green chlorine, and yellow sulfur.^[7] Various sulfide halides of Hg share the feature of being face-sharing [HgS₂X₄]⁻⁶ polyhedral, with X=Cl in the case of corderoite.

The main occurrence of corderoite in the type locality is in the Upper Miocene playa sediments within a thick zone, around 5–7 m (16–23 ft), sub parallel to bedding. Lake sediments including altered rhyolitic tuff and ash were deposited on the Tertiary rhyolitic volcanic rocks. Corderoite occurs as isolated grains or with cinnabar as replacements. Corderoite occurs as a low temperature supergene mineral.^[6]

• Grenchischev O. K. and Vasil'ev V. I. (1978) "First find of Corderoite (Hg₃S₂Cl₂) in mercury ores of USSR". Doklady. 246/1-6, 145.
• Keller P., Lissner F., and Schleid T. (2005) "Single-crystal structure determination of Perroudite, Hg₅Ag₄S₅ (I,Br)₂Cl₂, from Tsumeb (Namiba), and its structural relationships to other sulfide halides of mercury and cinnabar." Stuttgart 181/1, 1–9.
• Lavrent'ev Y. G. and Vasil'ev V. I. (1986) "New finds and data on the composition of corderoite (Hg₃S₂Cl₂)". Soviet Geology and Geophysics, 27/12, 117–121.
• Modreski P. J. (1998) "Eugene Edward Foord, 1946–1998". The Canadian Mineralogist, 36/2, 251–254.