Cryptophane

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General structure of cryptophanes: syn and anti diastereomeric forms

Cryptophanes are a class of organic supramolecular compounds studied and synthesized primarily for molecular encapsulation and recognition. One possible noteworthy application of cryptophanes is encapsulation and storage of hydrogen gas for potential use in fuel cell automobiles. Cryptophanes can also serve as containers in which organic chemists can carry out reactions that would otherwise be difficult to run under normal conditions. Due to their unique molecular recognition properties, cryptophanes also hold great promise as a potentially new way to study the binding of organic molecules with substrates, particularly as pertaining to biological and biochemical applications.[1]

Cryptophanes were discovered by André Collet and Jacqueline Gabard in 1981[2] when these researchers created, using template-directed synthesis, the first cryptophane, now known as cryptophane-A.

Structure

General classification

References

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