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Decabromodiphenyl ethane

Chemical compound From Wikipedia, the free encyclopedia

Decabromodiphenyl ethane is a chemical compound used as a brominated flame retardant. It was commercialised in the 1990s as an alternative for decabromodiphenyl ether,[1] following safety concern over that compound. The two molecules are chemically very similar, which gives them a similar application profile. Decabromodiphenyl ethane is now also coming under regulatory pressure.[2]

Quick facts Names, Identifiers ...
Decabromodiphenyl ethane
Names
IUPAC name
1,1'-ethane-1,2-diylbis(pentabromobenzene)
Other names
  • 1,2-Bis(perbromophenyl)ethane
  • 1,2-Bis(2,3,4,5,6-pentabromophenyl)ethane
  • 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.076.669 Edit this at Wikidata
EC Number
  • 284-366-9
UNII
  • Key: BZQKBFHEWDPQHD-UHFFFAOYSA-N
  • InChI=1S/C14H4Br10/c15-5-3(6(16)10(20)13(23)9(5)19)1-2-4-7(17)11(21)14(24)12(22)8(4)18/h1-2H2
  • C(CC1=C(C(=C(C(=C1Br)Br)Br)Br)Br)C2=C(C(=C(C(=C2Br)Br)Br)Br)Br
Properties
C14H4Br10
Molar mass 971.226 g·mol−1
Appearance White solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Uses

Decabromodiphenylethane is used as a flame retardant in a wide variety of materials including high-impact polystyrene (HIPS), acrylonitrile butadiene styrene (ABS), polyolefins and elastomers. Antimony trioxide is often included as a synergist. Its use in epoxy resins (used for circuit boards), HIPS and ABS (casings), wire and cable means that it is common in electronic devices.[3] The amount manufactured in China between 2006 and 2016 was 230,000 tons, of which 39,000 tons were exported from China in electrical appliances.[4] Under the REACH Regulation, it is registered for the manufacture in and/or the import to the European Economic Area in the tonnage band between 10 000 and 100 000 tonnes per year.[2] In e-waste, an average concentration of 340±200 ppm was found in a study conducted in 2011, confirming the widespread occurrence of the chemical in electronic equipment.[5]

Environmental occurrence

Decabromodiphenylethane was first detected in the environment in 2004.[6] It has been found in biota, air,[7] sediments,[8] sewage sludge,[1] and house dust.[9]

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