Diiodoacetylene

Chemical compound From Wikipedia, the free encyclopedia

Diiodoacetylene is the organoiodine compound with the formula C2I2. It is a white, volatile solid that dissolves in organic solvents. It is prepared by iodination of trimethylsilylacetylene.[1] Although samples explode above 80 °C, diiodoacetylene is the most readily handled of the dihaloacetylenes. Dichloroacetylene, for example, is more volatile and more explosive.[2] As confirmed by X-ray crystallography, diiodoacetylene is linear,[3] with the structure I−C≡C−I. It is however a shock-, heat-, and friction-sensitive compound. Like other haloalkynes, diiodoacetylene is a strong halogen bond donor.[4]

Quick facts Names, Identifiers ...
Diiodoacetylene
Names
Preferred IUPAC name
Diiodoethyne
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C2I2/c3-1-2-4
    Key: XANKMCMFEJCODV-UHFFFAOYSA-N
  • C(#CI)I
Properties
C2I2
Molar mass 277.831 g·mol−1
Appearance white solid
Density 3.43 g/cm3
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References

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