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Dioxazolone

Organic compound From Wikipedia, the free encyclopedia

In organic chemistry, a dioxazolone is a cyclic carbonate incorporated into C2NO2 ring. It is an uncommon heterocyclic compound. They arise by the phosgenation of hydroxamic acids:

RC(O)NHOH + COCl2 → RC=NO2CO + 2 HCl
General chemical structure of a 1,3,4-dioxazol-2-one

Although dioxazolones are often explosive, they are of interest as precursors to isocyanates:[1]

RC=NO2CO → R-N=C=O + CO2

Dioxazolones have attracted attention as reagents for the preparation of amides.[2]

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