Ekplexite

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Formula(Nb,Mo)S2•(Mg1−xAlx)(OH)2+x
Ekplexite
General
CategorySulfide mineral
Formula(Nb,Mo)S2•(Mg1−xAlx)(OH)2+x
IMA symbolEkp[1]
Crystal systemTrigonal
Crystal class3m, 32 or 3m
Space groupP321, P3m1, P3m1
Unit cella = 3.79, c = 11.3 [Å] (approximated)
Z = 2
Identification
ColorIron-black
Crystal habitmicaceous flakes (may be arranged in chaotic or radiating aggregates), in lenticular nests
Cleavage{001}, perfect
TenacityFlexible
Mohs scale hardness1
LusterMetallic
DiaphaneityOpaque
Density3.63
Pleochroismlight gray to dark gray (strong)
Common impuritiesW, V, Fe
References[2][3][4]

Ekplexite is a unique sulfide-hydroxide niobium-rich mineral with the formula (Nb,Mo)S2•(Mg1−xAlx)(OH)2+x.[5][3] It is unique because niobium is usually found in oxide or, eventually, silicate minerals. Ekplexite is a case in which chalcophile behaviour of niobium is shown, which means niobium present in a sulfide mineral. The unique combination of elements in ekplexite has to do with its name, which comes from a Greek world on "surprise".[5][3] The other example of chalcophile behaviour of niobium is edgarite, FeNb3S6, and both minerals were found in the same environment, which is a fenitic rock of Mt. Kaskasnyunchorr, Khibiny Massif, Kola Peninsula, Russia.[6] Analysis of the same rock has revealed the presence of two analogues of ekplexite, kaskasite (molybdenum-analogue) and manganokaskasite (molybdenum- and manganese-analogue). All three minerals belong to the valleriite group, and crystallize in the trigonal system with similar possible space groups.[7][3]

Beside niobium, molybdenum, sulfur, magnesium and aluminium ekplexite contains also relatively small amounts of tungsten, vanadium and iron.[5]

Association and environment

Crystal structure

References

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