Fulvene

Chemical compound From Wikipedia, the free encyclopedia

Fulvene (pentafulvene) is a hydrocarbon with the formula (CH=CH)2C=CH2. It is a prototype of a cross-conjugated hydrocarbon.[2] Fulvene is rarely encountered,[3] but substituted derivatives (fulvenes) are numerous. They are mainly of interest as ligands and precursors to ligands in organometallic chemistry.

Quick facts Names, Identifiers ...
Fulvene
Names
Preferred IUPAC name
5-Methylidenecyclopenta-1,3-diene[1]
Other names
Fulvene[1]
5-Methylene-1,3-cyclopentadiene
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
UNII
  • InChI=1S/C6H6/c1-6-4-2-3-5-6/h2-5H,1H2 checkY
    Key: PGTKVMVZBBZCKQ-UHFFFAOYSA-N checkY
  • InChI=1/C6H6/c1-6-4-2-3-5-6/h2-5H,1H2
    Key: PGTKVMVZBBZCKQ-UHFFFAOYAV
  • C=C1\C=C/C=C1
Properties
C6H6
Molar mass 78.114 g·mol−1
−42.9·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Fulvene is an isomer of benzene, which when irradiated at 237 to 254 nm forms small amounts of fulvene along with benzvalene.[4]

See also

References

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