Her interest in tourmaline turned out to be a career-long interest. Her paper, co-authored with M.J. Buerger, The Determination of the Crystal Structure of Tourmaline[5] led to 13 more papers on the same topic, including a definitive 1977 paper on the structural mechanism of pyroelectricity in tourmaline.[6]
She and her husband frequently collaborated and they published two editions of "Crystal Data" in 1954 and 1963 to compile the research of all crystallographers. Her area of expertise was in crystal chemistry and structural crystallography. She published more than 134 papers in her lifetime, almost half of which were collaborative projects with her husband.[7]
Donnay published Laboratory Manual in Crystallography based on her classes at McGill University. She also published Women in the Geological Sciences in Canada in an effort correct the injustices that she experienced in the male-dominated field of geology.[2] She was awarded the Past Presidents’ Medal of the Mineralogical Association of Canada in 1983.[2] She was the first women named to the Johns Hopkins Society of Scholar.[3] The mineral donnayite is named after her and Jose Donnay[2] and the mineral species Gaidonnayite is named after her.[7][8][9]