Heptafluoride

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Iodine heptafluoride's pentagonal bipyramidal structure

Heptafluoride typically refers to compounds with the formula RnMxF7y− or RnMxF7y+, where n, x, and y are independent variables and R any substituent.

The only binary heptafluorides are iodine heptafluoride (IF7), rhenium heptafluoride (ReF7), and gold heptafluoride (AuF7). Only IF7 and ReF7 are true heptafluorides, however, as AuF7 is actually a coordination complex of gold pentafluoride (AuF5) and molecular fluorine; therefore, the correct chemical formula of gold heptafluoride is actually AuF5·F2.[1]

Heptafluoride anions

Complex heptafluorides

References

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