Hydrocinnamaldehyde Chemical compound
From Wikipedia, the free encyclopedia
Hydrocinnamaldehyde is the organic compound with the formula C6 H5 CH2 CH2 CHO. It is produced by the hydrogenation of cinnamaldehyde . The compound is used in many mechanistic studies.[ 1] It is a common substrate in organic synthesis .[ 2] [ 3]
Quick facts Names, Identifiers ...
Hydrocinnamaldehyde
Names
Preferred IUPAC name
Other names
3-Phenylpropional; 3-Phenylpropionaldehyde; β-Phenylpropionaldehyde
Identifiers
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard
100.002.920
EC Number
UNII
InChI=1S/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,8H,4,7H2
Key: YGCZTXZTJXYWCO-UHFFFAOYSA-N
Properties
C 9 H 10 O
Molar mass
134.178 g·mol−1
Appearance
colorless liquid
Density
1.018 g/cm3
Melting point
−42 °C (−44 °F; 231 K)
Boiling point
224 °C (435 °F; 497 K)
Hazards
GHS labelling :
Warning
H315 , H319
P264 , P280 , P302+P352 , P305+P351+P338 , P321 , P332+P313 , P337+P313 , P362
Except where otherwise noted, data are given for materials in their
standard state (at 25
°C [77
°F], 100
kPa).
Close
Enache, Dan I.; Edwards, Jennifer K.; Landon, Philip; Solsona-Espriu, Benjamin; Carley, Albert F.; Herzing, Andrew A.; Watanabe, Masashi; Kiely, Christopher J.; Knight, David W.; Hutchings, Graham J. (2006). "Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO2 Catalysts". Science . 311 (5759): 362– 365. Bibcode :2006Sci...311..362E . doi :10.1126/science.1120560 . PMID 16424335 . S2CID 92890 .
Sasai, Hiroaki; Watanabe, Shizue; Suzuki, Takeyuki; Shibasaki, Masakatsu (2002). "Catalytic Asymmetric Synthesis of Nitroaldols Using a Lanthanum-Lithium-Binol Complex: (2S,3S)-2-Nitro-5-Phenyl-1,3-Pentanediol". Organic Syntheses . 78 : 14. doi :10.15227/orgsyn.078.0014 .
Abbott, Jason; Allais, Christophe; Roush, William R. (2015). "Enantioselective Reductive Syn-Aldol Reactions of 4-Acryloylmorpholine: Preparation of (2R, 3S)-3-Hydroxy-2-methyl-1-morpholino-5-phenylpentan-1-one". Organic Syntheses . 92 : 38– 57. doi :10.15227/orgsyn.092.0038 .