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Iron tetracarbonyl diiodide

Chemical compound From Wikipedia, the free encyclopedia

Iron tetracarbonyl diiodide is the inorganic compound with the formula FeI2(CO)4. The molecule features four carbonyl ligands and two iodides. It is a low-spin complex of ferrous iron. As confirmed by X-ray crystallography, the compound has cis stereochemistry.[1] It is a black solid that is soluble in dichloromethane and related organic solvents.

Quick facts Identifiers, Properties ...
Iron tetracarbonyl diiodide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/4CO.Fe.2HI/c4*1-2;;;/h;;;;;2*1H/q;;;;+2;;/p-2
    Key: BNIJVXICMSDYLX-UHFFFAOYSA-L
  • [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Fe](I)I
Properties
C4FeI2O4
Molar mass 421.694 g·mol−1
Appearance black solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation and reactions

It is prepared by the reaction of molecular iodine with iron pentacarbonyl, following a procedure first reported by Hieber and Wirschung in 1940:[2]

Fe(CO)5 + I2 → FeI2(CO)4 + CO

Iron tetracarbonyl diiodide reacts with a variety of Lewis bases with displacement of one or two CO ligands. The corresponding dibromide is even more reactive toward Lewis bases.[3][4]

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