Isotopes of cobalt

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Naturally occurring cobalt, Co, consists of a single stable isotope, 59Co (thus, cobalt is a mononuclidic element). Twenty-eight radioisotopes have been characterized; the most stable are 60Co with a half-life of 5.2714 years, 57Co (271.81 days), 56Co (77.24 days), and 58Co (70.84 days). All other isotopes have half-lives of less than 18 hours and most of these have half-lives of less than 1 second. This element also has 19 meta states, of which the most stable is 58m1Co with a half-life of 8.85 hours.

Quick facts Main isotopes, Decay ...
Isotopes of cobalt (27Co)
Main isotopes[1] Decay
Isotope abun­dance half-life (t1/2) mode pro­duct
56Co synth 77.24 d β+ 56Fe
57Co synth 271.81 d ε 57Fe
58Co synth 70.84 d β+ 58Fe
59Co 100% stable
60Co trace 5.2714 y β 60Ni
Standard atomic weight Ar°(Co)
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The isotopes of cobalt range in atomic weight from 50Co to 78Co. The main decay mode for isotopes with atomic mass less than that of the stable isotope, 59Co, is electron capture to iron isotopes, and the main mode of decay for those with greater mass is beta decay to nickel isotopes.

List of isotopes


More information Nuclide, Z ...
Nuclide
[n 1]
Z N Isotopic mass (Da)[4]
[n 2][n 3]
Discovery
year[5][6]
Half-life[1]
[n 4]
Decay
mode
[1]
[n 5]
Daughter
isotope

[n 6]
Spin and
parity[1]
[n 7][n 4]
Isotopic
abundance
Excitation energy[n 4]
50Co 27 23 49.98112(14) 1987 38.8(2) ms β+, p (70.5%) 49Mn (6+)
β+ (29.5%) 50Fe
β+, 2p? 48Cr
51Co 27 24 50.970647(52) 1987 68.8(19) ms β+ (96.2%) 51Fe 7/2−
β+, p (<3.8%) 50Mn
52Co 27 25 51.9631302(57) 1987 111.7(21) ms β+ 52Fe 6+
β+, p? 51Mn
52mCo 376(9) keV 2017 102(5) ms β+ 52Fe 2+
IT? 52Co
β+, p? 51Mn
53Co 27 26 52.9542033(19) 1970 244.6(28) ms β+ 53Fe 7/2−#
53mCo 3174.3(9) keV 1970 250(10) ms β+? (~98.5%) 53Fe (19/2−)
p (~1.5%) 52Fe
54Co 27 27 53.94845908(38) 1952 193.27(6) ms β+ 54Fe 0+
54mCo 197.57(10) keV 1967 1.48(2) min β+ 54Fe 7+
55Co 27 28 54.94199642(43) 1938 17.53(3) h β+ 55Fe 7/2−
56Co 27 29 55.93983803(51) 1941 77.236(26) d β+ 56Fe 4+
57Co 27 30 56.93628982(55) 1941 271.811(32) d EC 57Fe 7/2−
58Co 27 31 57.9357513(12) 1941 70.844(20) d EC (85.21%) 58Fe 2+
β+ (14.79%) 58Fe
58m1Co 24.95(6) keV 1950 8.853(23) h IT (99.9988%) 58Co 5+
EC (0.00120%) 58Fe
58m2Co 53.15(7) keV 1964 10.5(3) μs IT 58Co 4+
59Co 27 32 58.93319352(43) 1923 Stable 7/2− 1.0000
60Co 27 33 59.93381554(43) 1941 5.2714(6) y β 60Ni 5+ trace
60mCo 58.59(1) keV 1941 10.467(6) min IT (99.75%) 60Co 2+
β (0.25%) 60Ni
61Co 27 34 60.93247603(90) 1947 1.649(5) h β 61Ni 7/2−
62Co 27 35 61.934058(20) 1949 1.54(10) min β 62Ni (2)+
62mCo 22(5) keV 1949 13.86(9) min β (>99.5%) 62Ni (5)+
IT (<0.5%) 62Co
63Co 27 36 62.933600(20) 1960 26.9(4) s β 63Ni 7/2−
64Co 27 37 63.935810(21) 1969 300(30) ms β 64Ni 1+
64mCo 107(20) keV 2010 300# ms β? 64Ni 5+#
IT? 64Co
65Co 27 38 64.9364621(22) 1978 1.16(3) s β 65Ni (7/2)−
66Co 27 39 65.939443(15) 1985 194(17) ms β 66Ni (1+)
β, n? 65Ni
66m1Co 175.1(3) keV 1998 824(22) ns IT 66Co (3+)
66m2Co 642(5) keV 1998 >100 μs IT 66Co (8−)
67Co 27 40 66.9406096(69) 1985 329(28) ms β 67Ni (7/2−)
β, n? 66Ni
67mCo 491.55(11) keV 2008 496(33) ms IT (>80%) 67Co (1/2−)
β 67Ni
68Co 27 41 67.9445594(41) 1985 200(20) ms β 68Ni (7−)
β, n? 67Ni
68m1Co[n 8] 150(150)# keV 2000 1.6(3) s β 68Ni (2−)
β, n (>2.6%) 67Ni
68m2Co 195(150)# keV 2010 101(10) ns IT 68Co (1)
69Co 27 42 68.945909(92) 1985 180(20) ms β 69Ni (7/2−)
β, n? 68Ni
69mCo[n 8] 170(90) keV 2015 750(250) ms β 69Ni 1/2−#
70Co 27 43 69.950053(12) 1985 508(7) ms β 70Ni (1+)
β, n? 69Ni
β, 2n? 68Ni
70mCo[n 8] 200(200)# keV 2000 112(7) ms β 70Ni (7−)
IT? 70Co
β, n? 69Ni
β, 2n? 68Ni
71Co 27 44 70.95237(50) 1992 80(3) ms β (97%) 71Ni (7/2−)
β, n (3%) 70Ni
72Co 27 45 71.95674(32)# 1992 51.5(3) ms β (<96%) 72Ni (6−,7−)
β, n (>4%) 71Ni
β, 2n? 70Ni
72mCo[n 8] 200(200)# keV 2016 47.8(5) ms β 72Ni (0+,1+)
73Co 27 46 72.95924(32)# 1995 42.0(8) ms β (94%) 73Ni (7/2−)
β, n (6%) 72Ni
β, 2n? 71Ni
74Co 27 47 73.96399(43)# 1995 31.3(13) ms β (82%) 74Ni 7−#
β, n (18%) 73Ni
β, 2n? 72Ni
75Co 27 48 74.96719(43)# 1995 26.5(12) ms β (>84%) 75Ni 7/2−#
β, n (<16%) 74Ni
β, 2n? 73Ni
76Co 27 49 75.97245(54)# 2010 23(6) ms β 76Ni (8−)
β, n? 75Ni
β, 2n? 74Ni
76m1Co[n 8] 100(100)# keV 2015 16(4) ms β 76Ni (1−)
76m2Co 740(100)# keV 2015 2.99(27) μs IT 76Co (3+)
77Co 27 50 76.97648(64)# 2014 15(6) ms β 77Ni 7/2−#
β, n? 76Ni
β, 2n? 75Ni
β, 3n? 74Ni
78Co 27 51 77.983 55(75)# 2017 11# ms
[>410 ns]
β? 78Ni
79Co[7] 27 52 2026
80Co[7] 27 53 2026
This table header & footer:
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  1. mCo  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Bold symbol as daughter  Daughter product is stable.
  6. () spin value  Indicates spin with weak assignment arguments.
  7. Order of ground state and isomer is uncertain.

| β | 77Ni | rowspan=4|7/2−# | rowspan=4| |- | β, n? | 76Ni |- | β, 2n? | 75Ni |- | β, 3n? | 74Ni |-id=Cobalt-78 | 78Co | style="text-align:right" | 27 | style="text-align:right" | 51 | 77.983 55(75)# | style="text-align:center" | 2015 | 11# ms
[>410 ns] | β? | 78Ni | | |-id=Cobalt-79 | 79Co[7] | style="text-align:right" | 27 | style="text-align:right" | 52 | | style="text-align:center" | 2014 | | | | | |-id=Cobalt-80 | 80Co[7] | style="text-align:right" | 27 | style="text-align:right" | 53 | | style="text-align:center" | 2017 | | | | | |-

! colspan="20" style="text-align:right; line-height:85%;" |

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Stellar nucleosynthesis of cobalt-56

One of the terminal nuclear reactions in stars prior to supernova produces 56Ni. 56Ni then decays to 56Co, which then decays to 56Fe. These decays power the luminosity displayed in light decay curves. Both the light decay and radioactive decay curves are expected to be exponential. Therefore, the light decay curve should give an indication of the nuclear reactions powering it. This has been confirmed by observation of bolometric light decay curves for SN 1987A. Between 600 and 800 days after SN1987A occurred, the bolometric light curve decreased at an exponential rate with half-life values from 68.6 days to 69.6 days.[8] The rate at which the luminosity decreased closely matched that expected of exponential decay of 56Co.

Cobalt-57

Cobalt-57 (57Co or Co-57) is used in medical tests; it is used as a radiolabel for vitamin B12 uptake. It is useful for the Schilling test.[9]

57Co is used as a source of gamma rays in Mössbauer spectroscopy of iron-containing samples. Electron capture by 57Co forms an excited state of the 57Fe nucleus, which in turn decays to the ground state with the emission of a gamma ray. Measurement of the gamma-ray spectrum provides information about the chemical state of the iron atom in the sample.

Cobalt-60

Cobalt-60 (60Co or Co-60) is used in radiotherapy. It produces two gamma rays with energies of 1.17 MeV and 1.33 MeV. The 60Co source is about 2 cm in diameter and as a result produces a geometric penumbra, making the edge of the radiation field fuzzy. The metal has the unfortunate habit of producing fine dust, causing problems with radiation protection.[citation needed] The 60Co source is useful for about 5 years but even after this point is still very radioactive, and so cobalt machines have fallen from favor in the Western world where linacs are more usual.

Cobalt-60 (60Co) is useful as an industrial gamma ray source also: uses for industrial cobalt include

See also

References

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