Born in Yuncler in the Province of Toledo, Orozco was one of a number of players from his province to make it into the Atlético Madrid first team in the 1960s and 1970s.[1] He made his debut in La Liga on 21 September 1969 in the second game of the season, playing the last five minutes of a 2–1 home loss to Las Palmas as a substitute for Javier Irureta.[4] A week later on his first start, he scored in a 2–0 home win over Valencia, eventually making four appearances in a title-winning season.[5]
In 1971–72, Orozco scored a career-best 10 top-flight goals, including four on 5 December in a 5–0 win over Real Sociedad at the Vicente Calderón Stadium; only Luis Aragonés in 1967 had scored four in a game for the team before.[6] He finished the season on 8 July with the 1972 Copa del Generalísimo final, playing the last 19 minutes in place of injured goalscorer José Eulogio Gárate in a 2–1 victory over Valencia.[7]
In July 1973, former Atlético manager Marcel Domingo signed Orozco amidst interest from Barcelona. The player received a three-year contract with a combined salary of 7 million Spanish pesetas and his former club received 8 million.[8]
On 27 April 1980, with Málaga already relegated by the 31st matchday, the team were to take on relegation-threatened Salamanca. The visiting club's manager Felipe Mesones enlisted his former player Raúl Castronovo of Algeciras – a former Málaga teammate of Orozco – to present the offer of 4.4 million pesetas for Málaga to lose. Salamanca's 3–0 win is the only game in La Liga history to have been voided for match-fixing, though that club still avoided relegation. Orozco was one of five Málaga players suspended over the fix, being banned from football for two years.[3][2]