Karsil

Chemical compound From Wikipedia, the free encyclopedia

Karsil (also called erlüjixiancaoan) is an acylanilide herbicide, similar to propanil. It is potent against annual grasses and broadleaved weeds in celery, and a strong inhibitor of photosynthesis.[3] It is approved for use in China.[1]

Quick facts Names, Identifiers ...
Karsil
Names
Preferred IUPAC name
N-(3,4-Dichlorophenyl)-2-methylpentanamide
Other names
  • (2RS)-3′,4′-Dichloro-2-methylpentananilide
  • (RS)-3′,4′-Dichloro-2-methylvaleranilide
  • N-(3,4-Dichlorophenyl)-2-methylpentanamide[1]
  • NIA 4562
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/C12H15Cl2NO/c1-3-4-8(2)12(16)15-9-5-6-10(13)11(14)7-9/h5-8H,3-4H2,1-2H3,(H,15,16)
    Key: VUNCGGHZBFQRPB-UHFFFAOYSA-N
  • CCCC(C)C(=O)NC1=CC(=C(C=C1)Cl)Cl
Properties
C12H15Cl2NO
Molar mass 260.16 g·mol−1
Density 1222 kg/m3[2]
Melting point 106 °C (223 °F; 379 K)[2]
Boiling point 396[2] °C (745 °F; 669 K)
Vapor pressure 1.79 nmHg[2]
Hazards
Flash point 193[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Close

When degraded by bacteria, karsil becomes 3,4-dichloroaniline and 3,3',4,4,'-tetrachloroazobenzene.[3] Karsil is theorised to form hydrogen bonds with the protein of an enzyme involved in the oxidation of water, creating its herbicidal potential, similar to diuron and atrazine.[4]

Karsil has been manufactured by Niagara Chemical Division.[5] If ingested, activated charcoal absorbs it.[6] Karsil is ten times as active as atrazine at the chloroplast level.[7]

References

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