Kentbrooksite

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Formula(Na,REE)15(Ca,REE)6Mn3Zr3NbSi25O74F2·2H2O (original form)
Strunz classification9.CO.10 (10 ed)
8/E.23-20 (8 ed)
Kentbrooksite
General
CategorySilicate mineral, Cyclosilicate
Formula(Na,REE)15(Ca,REE)6Mn3Zr3NbSi25O74F2·2H2O (original form)
IMA symbolKtb[1]
Strunz classification9.CO.10 (10 ed)
8/E.23-20 (8 ed)
Dana classification64.1.2.1
Crystal systemTrigonal
Crystal classDitrigonal pyramidal (3m)
H-M symbol: (3m)
Space groupR3m
Unit cella = 14.24, c = 30.03 [Å] (approximated); Z = 3
Identification
ColorYellow-brown
Crystal habitaggregates (anhedral to subhedral)
CleavageNone
FractureUneven
TenacityBrittle
Mohs scale hardness5–6
LusterVitreous
StreakWhite
DiaphaneityTransparent
Density3.10 (measured)
Optical propertiesUniaxial (−)
Refractive indexnω = 1.63, nε = 1.62 (approximated)
PleochroismNone
Other characteristicsPyroelectric
References[2][3]

Kentbrooksite is a moderately rare mineral of the eudialyte group,[2] with chemical formula (Na,REE)15(Ca,REE)6Mn3Zr3NbSi[(Si9O27)2(Si3O9)2O2]F2·2H2O.[3] This extended formula shows the presence of cyclic silicate groups and dominance of Si at the M4 site, according to the nomenclature of the eudialyte group.[4] The characteristic features of kentbrooksite, that make it different from eudialyte are: (1) dominancy of fluorine (the only currently known example among the whole group[2]), (2) dominancy of manganese, and (3) dominancy of niobium. Trace hafnium and magnesium are also reported.[3] Kentbrooksite is relatively common when compared to most other species of the group.[2]

Notes on chemistry

References

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