Khomyakovite

Mineral of the eudialyte group From Wikipedia, the free encyclopedia

Khomyakovite is an exceedingly rare mineral of the eudialyte group, with formula Na12Sr3Ca6Fe3Zr3W(Si25O73)(O,OH,H2O)3(OH,Cl)2.[2][3] The original formula was extended to show the presence of both the cyclic silicate groups and M4-site silicon, according to the nomenclature of the eudialyte group.[4] Some niobium substitutes for tungsten in khomyakovite. Khomyakovite is an iron-analogue of manganokhomyakovite, the second mineral being a bit more common.[3] The two minerals are the only group representatives, beside taseqite, with species-defining strontium, although many other members display strontium diadochy. Khomyakovite is the third eudialyte-group mineral with essential tungsten (after johnsenite-(Ce) and manganokhomyakovite).[2]

FormulaNa12Sr3Ca6Fe3Zr3W(Si25O73)(O,OH,H2O)3(OH,Cl)2 (original form)
Strunz classification9.CO.10 (10 ed)
8/E.23-30 (8 ed)
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Khomyakovite
General
CategorySilicate mineral, cyclosilicate
FormulaNa12Sr3Ca6Fe3Zr3W(Si25O73)(O,OH,H2O)3(OH,Cl)2 (original form)
IMA symbolKmy[1]
Strunz classification9.CO.10 (10 ed)
8/E.23-30 (8 ed)
Dana classification64.1.2.5
Crystal systemTrigonal
Crystal classDitrigonal pyramidal (3m)
H-M symbol: (3m)
Space groupR3m
Unit cella = 14.30, c = 30.08 [Å] (approximated); Z = 3
Identification
ColorOrange to orange-red
Crystal habitAggregates (anhedral to subhedral)
CleavageNone
FractureUneven
TenacityBrittle
Mohs scale hardness5–6
LusterVitreous
StreakWhite
DiaphaneityTransparent to translucent
Density3.14 (calculated)
Optical propertiesUniaxial (−)
Refractive indexnω = 1.63, nε = 1.63 (approximated)
PleochroismNone
References[2][3]
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Occurrence and association

Khomyakovite, manganokhomyakovite, johnsenite-(Ce) and oneillite are four eudialyte-group minerals with type locality in Mont Saint-Hilaire, Quebec, Canada.[5] Khomyakovite itself is associated with analcime, annite, natrolite, titanite, calcite, and pyrite.[3]

Notes on chemistry

Impurities in khomyakovite include niobium, potassium and manganese, with minor rare earth elements, magnesium, titanium, hafnium and aluminium.[3]

References

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