Lanthanum disilicide

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Lanthanum disilicide
Names
Other names
Lanthanum silicide
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 235-017-4
  • InChI=1S/La.2Si
    Key: QVKFOXYBEQWBNY-UHFFFAOYSA-N
  • [Si].[La].[Si]
Properties
LaSi2
Molar mass 195.075 g·mol−1
Appearance gray crystals
Density 5.05 g/cm3
Melting point 1,500[1] °C (2,730 °F; 1,770 K)
insoluble
Structure
Tetragonal, orthorhombic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lanthanum disilicide is a binary inorganic compound of lanthanum metal and silicon with the formula LaSi2. Many other lanthanum silicides are known.[2]

  • Combine silicon and lanthanum powders, compress the mixture into solid blocks, and melt under vacuum conditions.[3]
  • React lanthanum, silicon, and mercury in a quartz tube at 450 °C for 10–12 hours. Subsequently, eliminate surplus mercury through distillation, followed by annealing the resultant material at 450–600 °C.[3]

Physical properties

Lanthanum disilicide forms gray crystals. LaSi2 can exist in two crystal structures: tetragonal (α-GdSi2 type) and orthorhombic (α-ThSi2 type).[1][4]

The compound is known for its metallic behavior and various applications.[5]

Chemical properties

Uses

References

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