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Lithium hexafluorostannate

Chemical compound From Wikipedia, the free encyclopedia

Lithium hexafluorostannate is an inorganic chemical compound with the chemical formula Li2SnF6.[1][2]

Quick facts Names, Identifiers ...
Lithium hexafluorostannate
Names
IUPAC name
Dilithium hexafluorostannate(2-)
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/6FH.2Li.Sn/h6*1H;;;/q;;;;;;2*+1;+4/p-6
    Key: LDTWGZJNXIAELR-UHFFFAOYSA-H
  • [Li+].[Li+].F[Sn-2](F)(F)(F)(F)F
Properties
F6Li2Sn
Molar mass 246.58 g·mol−1
Appearance White powder
Density g/cm3
Insoluble
Hazards
GHS labelling:
Danger
H301, H315, H319, H335
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

The compound can be prepared by reacting ammonium hexachlorostannate, lithium carbonate, and fluorine gas at 400 °C,[3] or by reacting lithium stannate with hydrofluoric acid.[4]

Physical properties

The compound forms white crystals of the monoclinic system.[5][6]

Lithium hexafluorostannate forms a dihydrate.[7]

References

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