Lithium triborate

Chemical compound From Wikipedia, the free encyclopedia

Lithium triborate (LiB3O5) or LBO is a non-linear optical crystal. It has a wide transparency range, moderately high nonlinear coupling, high damage threshold and desirable chemical and mechanical properties. This crystal is often used for second harmonic generation (SHG, also known as frequency doubling), for example of Nd:YAG lasers (1064 nm → 532 nm). LBO can be both critically and non-critically phase-matched. In the latter case the crystal has to be heated or cooled depending on the wavelength.

Quick facts Identifiers, Properties ...
Lithium triborate
__Li+     __ B3+     __ O2−
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/B3O5.Li/c4-1-7-3(6)8-2-5;/q-1;+1
    Key: VCZFPTGOQQOZGI-UHFFFAOYSA-N
  • [Li+].B(=O)OB([O-])OB=O
Properties
LiB3O5
Molar mass 119.37 g·mol−1
Appearance Colorless crystalline solid
Density 2.747 g/cm3
Melting point 834 °C (1,533 °F; 1,107 K)
1.5656
Structure
Orthorhombic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lithium triborate was discovered and developed by Chen Chuangtian and others of the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. It has been patented.[1]

Chemical properties

Applications of lithium triborate (LBO) crystal

Lithium triborate (LBO) crystals are applicable in various nonlinear optical applications:[2]

References

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