Meisenheimer rearrangement

From Wikipedia, the free encyclopedia

Meisenheimer rearrangement
Named after Jakob Meisenheimer
Reaction type Rearrangement reaction

In organic chemistry, the Meisenheimer rearrangement is the conversion of a tertiary amine oxide to a alkoxylamine. The reaction is most common for benzylic or allylic amine oxides.[1][2] The reaction is names for Jakob Meisenheimer.[3] The process resembles the oxy-Cope rearrangement.

The 1,2-rearrangement:

Meisenheimer 1,2-rearrangement

The 2,3-rearrangement:

Meisenheimer 2,3-rearrangement

Related Articles

Wikiwand AI