Multiple antisymmetry

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In crystallography and materials science multiple antisymmetry is the concept of a substance possessing two or more different types of antisymmetry simultaneously. Multiple antisymmetry has applications in the fields of magnetic structures, ferroelectricity, and the physical properties of crystals.

Antisymmetry operation

Antisymmetry is a symmetry operation which reverses an object to its opposite.[1] A more precise definition is "operations of antisymmetry transform objects possessing two possible values of a given property from one value to the other."[2]

An antisymmetry can be any two-valued operation which, if executed twice, returns the object to its original state. In the 1930s the first use of an antisymmetry operation was dichromatic symmetry or black-white symmetry.[3][4][5] In 1951 Landau and Lifshitz reinterpreted black and white colours to correspond to time-reversal symmetry.[6]

A wide variety of antisymmetries are now recognized, with three new antisymmetries having been discovered since 2010.[7]

Two-valued symmetries (antisymmetries)
Antisymmetry Transformation Symbol[7] Refs.
Black-white (2-colour) [8][9]
Space inversion [10]
Time-reversal or [6][11]
Charge-reversal or [12]
Magnetic moment or [13]
Rotation-reversal [14]
Distortion-reversal [15][16][17]
Wedge reversion [18]

A symmetry operation which interchanges three or more colours is not an antisymmetry but rather a polychromatic or colour symmetry.

Multiple antisymmetry

Combination of two antisymmetries
Combination of three antisymmetries (cyan, magenta and yellow)

If two different antisymmetry operations are defined (for example and ) they can be used to generate double antisymmetry groups.[7]:259–260[19]

Where there are different types of antisymmetry operations the total number of antisymmetry combinations is . The table below lists the total number of point groups and space groups in 3D for 0, 1, 2, 3 and 4 different types of antisymmetries.

Multiple antisymmetry groups
GroupSymbol[20]NumberRefs.
Point groups in 3D032[21]
1122[4][8][9]
2624[19][22]
34362[23]
442244[23]
Space groups in 3D0230[24]
11651[25][26]
217803[19][22]
3287574[15]
46880800[23]

Applications

Simultaneously with the theoretical investigations of A. M. Zamorzaev, practical applications of double antisymmetry were being pursued by other Russian researchers such as B. A. Tavger, B. K. Vainshtein and L. A. Shuvalov.

In 1962 Shuvalov and N. V. Belov used two different types of antisymmetry to describe the combination of ferromagnetic and ferroelectric properties of crystals.[27][28] This field is now termed multiferroics, and has been an intensive area of research since 2000.[29] Magnetochromism is a related field in which magnetic moment and black-white antisymmetries are combined.[30]

Space-time reversal (inverting both space and time coordinates, signified by ) was discussed by Yu. I. Sirotin and M. P. Shaskolskaya in 1982,[31] and was used to derive the ferroelectric space groups in 1986.[32] Antiparticle conjugation is related to space-time reversal.[7]:256

The combination of space reversal and magnetic reversal was studied by Vojtěch Kopský in 2006.[33]

Rotation-reversal space groups have been used in the classification of tilted octahedra perovskites.[34][19]

History

Notes

References

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